| 723251-61-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 723251-61-4
• 化学式: C₃₈H₃₈N₃O₅PPd
• 分子量: 754.131
• InChiKey: LNHIHXAMZZIGGP-UMUBBOJSSA-M

反应信息

• 作为产物：
  描述：

  chloromethyl(1,5-cyclooctadiene)palladium(II) 、 、 三苯基膦 以 苯 为溶剂， 以77.2%的产率得到
  参考文献：
  名称：

  Synthesis, structure and norbornene polymerization behavior of neutral palladium complexes

  摘要：

  A series of neutral palladium(II) complexes bearing non-symmetric bidentate pyrrole-iminato or salicylaldiminato chelate ligands have been synthesized, and the structure of representative complexes (3a, 4a, and 5a) have been confirmed by X-ray crystallographic analysis. These palladium complexes have been investigated as catalysts for the polymerization of norbornene. Using modified methylaluminoxane (MMAO) as a cocatalyst, these complexes display high activities and produce vinyl-addition polynorborenes. Catalytic activity of up to 8.52 x 10(3) kg/mol(Pd) h has been observed. Wide-angle X-ray diffraction (WAXD) has been used to investigate the polymer microstructure and it has been found that they are non-crystalline. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.03.017