[Pt(1,2-bis(benzylthio)ethylene-1,2-dithiolate)(2,2'-bipyridine)] | 220294-67-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Pt(1,2-bis(benzylthio)ethylene-1,2-dithiolate)(2,2'-bipyridine)]
• 英文别名: (Z)-1,2-bis(benzylsulfanyl)ethene-1,2-dithiolate;platinum(2+);2-pyridin-2-ylpyridine
• CAS: 220294-67-7
• 化学式: C₂₆H₂₂N₂PtS₄
• 分子量: 685.818
• InChiKey: VFEWUZDYVQYBLP-NDXGFPCWSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pt(1,2-bis(benzylthio)ethylene-1,2-dithiolate)(2,2'-bipyridine)] 、 碘 以 正己烷 为溶剂， 生成 [Pt(1,2-bis(benzylthio)ethylene-1,2-dithiolate)(2,2'-bipyridine)]I1.9
  参考文献：
  名称：

  Preparation spectroscopy and conductivity of [Pt(SS)(NN)]-type complexes and their iodine oxidized complexes

  摘要：

  Complexes of the general formula [Pt(SS)(NN)] have been prepared, where SS is bbdt(1,2-bis(benzylthio)ethylene-1,2-dithiolate) or dpdt (5,6-dihydrophenyl-1,4-dithion-2,3-dithiolate) and NN is bipy (2,2'-bipyridine) or phen (1,10-phenanthroline). The UV-Vis spectra exhibit intense intramolecular ligand-to-ligand charge transfer absorption bands at 440-600 nm. Cyclic voltammograms show a reversible oxidation step assigned to [Pt(SS)(NN)](0)/[Pt(SS)(NN)](+). On doping iodine into the complexes, partial oxidation occurs to afford [Pt(SS)(NN)I-x (x=1.9(2.2). IR, Raman and ESR spectra of the iodine-doped complexes are discussed. Electrical conductivities of the neutral mixed-ligand complexes (10(-9)-10(-10) S cm(-1)) increase to 10(-6)-10(-7) S cm(-1) upon It doping. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00259-x
• 作为产物：
  描述：

  (2,2-联吡啶)二氯铂(II) 、 4,5-bis(benzylthio)-1,3-dithiole-2-one 在 sodium 作用下， 以 甲醇 、 二甲基亚砜 为溶剂， 生成 [Pt(1,2-bis(benzylthio)ethylene-1,2-dithiolate)(2,2'-bipyridine)]
  参考文献：
  名称：

  Preparation spectroscopy and conductivity of [Pt(SS)(NN)]-type complexes and their iodine oxidized complexes

  摘要：

  Complexes of the general formula [Pt(SS)(NN)] have been prepared, where SS is bbdt(1,2-bis(benzylthio)ethylene-1,2-dithiolate) or dpdt (5,6-dihydrophenyl-1,4-dithion-2,3-dithiolate) and NN is bipy (2,2'-bipyridine) or phen (1,10-phenanthroline). The UV-Vis spectra exhibit intense intramolecular ligand-to-ligand charge transfer absorption bands at 440-600 nm. Cyclic voltammograms show a reversible oxidation step assigned to [Pt(SS)(NN)](0)/[Pt(SS)(NN)](+). On doping iodine into the complexes, partial oxidation occurs to afford [Pt(SS)(NN)I-x (x=1.9(2.2). IR, Raman and ESR spectra of the iodine-doped complexes are discussed. Electrical conductivities of the neutral mixed-ligand complexes (10(-9)-10(-10) S cm(-1)) increase to 10(-6)-10(-7) S cm(-1) upon It doping. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00259-x