Mixed‐Ligand Complexes of Ni(II), Cu(II), and Zn(II) with 5‐Chlorosalicylaldehyde and β‐Diketones
摘要:
Mixed-ligand complexes of the types M(5-Clsa1)L and Ni(5-Clsal)L(H2O)(2) (where M = copper(II) or zinc(II), 5-Clsa1H = 5-chlorosalicylaldehyde and HL = 2,4-pentanedione, 1-phenyl-1,3-butanedione, or 1,3-diphenyl-1.3-propanedione) have been synthesized by I : I : I molar reactions of metal chlorides with 5-chlorosalicylaldehyde and beta-diketones. The resulting complexes have been characterized by elemental analyses, TLC, conductances, thermal analysis, magnetic moments, IR, electronic, and H-1 NMR spectra.