(diethyl(phenyl)phosphine)3Ag(trimethylsilylselenolato) | 935681-90-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (diethyl(phenyl)phosphine)3Ag(trimethylsilylselenolato)
• CAS: 935681-90-6
• 化学式: C₃₃H₅₄AgP₃SeSi
• 分子量: 758.627
• InChiKey: PWFIVPVKSFLCKC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.49
• 重原子数：
  39.0
• 可旋转键数：
  14.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  双(三甲基硅烷基)硒醚 、 silver(I) acetate 、 二乙基苯膦 以 乙醚 为溶剂， 以58%的产率得到(diethyl(phenyl)phosphine)3Ag(trimethylsilylselenolato)
  参考文献：
  名称：

  New Copper and Silver Trimethylsilylchalcogenolates

  摘要：

  The synthesis and characterization of the copper and silver trimethylsilylchalcogenolates (EtPh2P)(3)MESiMe3 and (Et2PhP)(3)MESiMe3 (M = Cu-I, Ag-I) are reported. These chalcogenolate complexes can be prepared in high yield; however, they are thermally unstable. Low-temperature single-crystal X-ray analysis of (EtPh2P)(3)CuSSiMe3 (1b) and (Et2PhP)(3)CuSeSiMe3 (2a) confirms the terminal coordination of the chalcogen ligand and the tetrahedral coordination about the metal. Protonolysis of 2a with EtOH yields the terminal selenol complex (Et2PhP)(3)CuSeH (6). Reaction of 1b with EtPh2P-solubilized AgOAc yields the heterometallic cluster [Cu9Ag3S6(PEtPh2)(8)] (7) in good yield.

  DOI：

  10.1021/ic0618910