DPEphos | 923039-20-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: DPEphos
• 英文别名: Phosphine, 1,1'-(thiodi-2,1-phenylene)bis[1,1-diphenyl-；[2-(2-diphenylphosphanylphenyl)sulfanylphenyl]-diphenylphosphane
• CAS: 923039-20-7
• 化学式: C₃₆H₂₈P₂S
• 分子量: 554.632
• InChiKey: APUVVHHWRLVTPD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.4
• 重原子数：
  39
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• LUMINESCENT SILVER COMPLEXES
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2360162A1

  公开（公告）日：2011-08-24

  An luminescent device material which is inexpensive and exhibits excellent durability in the presence of oxygen can be provided using a luminescent silver complex which has an organic multidentate ligand, particularly, a luminescent silver complex wherein the organic multidentate ligand is coordinated to a phosphorus atom, a nitrogen atom, an oxygen atom, a sulfur atom, an arsenic atom, an oxygen anion, a nitrogen anion, or a sulfur anion, or a polymer of the luminescent silver complex.

  可以使用含有有机多齿配体的发光银配合物来提供一种在氧气存在的情况下具有极好耐久性且价格低廉的发光器件材料，特别是一种含有有机多齿配体的发光银配合物，其中有机多齿配体与磷原子、氮原子、氧原子、硫原子、砷原子、氧负离子、氮负离子或硫负离子配位，或者是该发光银配合物的聚合物。
• METAL COMPLEX HAVING AROMATIC RING LIGAND CONTAINING NITROGEN ATOM
  申请人：Kuramochi Yusuke

  公开号：US20120041203A1

  公开（公告）日：2012-02-16

  A metal complex containing a nitrogen-containing aromatic ring ligand which has a dendritic molecular chain, and a copper(I) ion or a silver(I) ion. For example, the metal complex which is represented by compositional formula (8): (wherein M + is a copper(I) ion or a silver(I) ion, L is a ligand, and X is a counter ion; p is a positive number, and q and r are each independently numerical numbers of 0 or more; R represents a hydrogen atom, a halogen atom, a cyano group, a nitro group, a carboxyl group, an amino group, an acylamino group, a silyl group, a hydroxyl group, an acyl group, a hydrocarbyl group, a hydrocarbyloxy group, a hydrocarbylthio group, or a heterocyclic group, wherein the amino group, the silyl group, the hydrocarbyl group, the hydrocarbyloxy group and the hydrocarbylthio group optionally have a substituent) has excellent heat resistance.

  一种含有氮杂环配体的金属络合物，其具有树枝状分子链，以及铜(I)离子或银(I)离子。例如，由组成式(8)表示的金属络合物：（其中M+为铜(I)离子或银(I)离子，L为配体，X为反离子；p为正数，q和r分别为大于等于0的数字；R代表氢原子、卤原子、氰基、硝基、羧基、氨基、酰胺基、硅基、羟基、酰基、烃基、烃氧基、烃硫基或杂环基，其中氨基、硅基、烃基、烃氧基和烃硫基可选地具有取代基）具有优异的耐热性。
• METAL COMPLEX HAVING AROMATIC LIGAND THAT CONTAINS NITROGEN ATOM
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2423192A1

  公开（公告）日：2012-02-29

  A metal complex containing a nitrogen-containing aromatic ring ligand which has a dendritic molecular chain, and a copper(I) ion or a silver(I) ion. For example, the metal complex which is represented by compositional formula (8) : (wherein M+ is a copper(I) ion or a silver(I) ion, L is a ligand, and X is a counter ion; p is a positive number, and q and r are each independently numerical numbers of 0 or more; R represents a hydrogen atom, a halogen atom, a cyano group, a nitro group, a carboxyl group, an amino group, an acylamino group, a silyl group, a hydroxyl group, an acyl group, a hydrocarbyl group, a hydrocarbyloxy group, a hydrocarbylthio group, or a heterocyclic group, wherein the amino group, the silyl group, the hydrocarbyl group, the hydrocarbyloxy group and the hydrocarbylthio group optionally have a substituent) has excellent heat resistance.

  一种含有含氮芳香环配体的金属络合物，该配体具有树枝状分子链，以及铜(I)离子或银(I)离子。例如，由组成式 (8) ： (其中 M+ 是铜(I)离子或银(I)离子，L 是配体，X 是反离子；p 是正数，q 和 r 分别独立地为 0 或以上的数字；R 代表氢原子、卤素原子、氰基、硝基、羧基、氨基、酰氨基、硅烷基、羟基、酰基、烃基、烃比氧基、烃硫基或杂环基，其中氨基、硅烷基、烃基、烃比氧基和烃硫基可选择具有取代基）具有优异的耐热性。
• LUMINESCENT SILVER COMPLEX
  申请人：Kobayashi Norifumi

  公开号：US20110309304A1

  公开（公告）日：2011-12-22

  An luminescent device material which is inexpensive and exhibits excellent durability in the presence of oxygen can be provided using a luminescent silver complex which has an organic multidentate ligand, particularly, a luminescent silver complex wherein the organic multidentate ligand is coordinated to a phosphorus atom, a nitrogen atom, an oxygen atom, a sulfur atom, an arsenic atom, an oxygen anion, a nitrogen anion, or a sulfur anion, or a polymer of the luminescent silver complex.
• [EN] MEMBRANE CONTAINING SILVER COMPLEX<br/>[FR] MEMBRANE CONTENANT UN COMPLEXE D'ARGENT
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2011152358A1

  公开（公告）日：2011-12-08

  　白金族金属の錯体と比べて安価であり、発光材料として酸素存在下における耐久性に優れた錯体を使用する膜を提供する。本発明の膜は、組成式（１）：（Ａｇ+）（Ｌ1）a（Ｌ2）b（Ｌ3）c（Ｘ1）d（Ｌ1はリン原子を１つ以上と、窒素原子、酸素原子、硫黄原子、ヒ素原子、酸素アニオン及び硫黄アニオンから選ばれる１つ以上とを合計で３つ以上６つ以下有する分子である。Ｌ2は前記原子及びイオンから選ばれる原子及びイオンを合計で２つ有する分子である。Ｌ3は前記原子又はイオンを１つ有する分子である。Ｘ1はアニオンである。ａは０．５より大きい数であり、ｂ、ｃ及びｄはそれぞれ独立に０以上の数である。）で表される銀錯体を含む。