6-bromo-2,11-dithia[3.3]orthocyclophane | 1190622-39-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 芳基卤化物
• 英文名称: 6-bromo-2,11-dithia[3.3]orthocyclophane
• CAS: 1190622-39-9
• 化学式: C₁₆H₁₅BrS₂
• 分子量: 351.331
• InChiKey: RBGBHOQGXCLHBX-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  二茂铁乙炔 、 6-bromo-2,11-dithia[3.3]orthocyclophane 在 Pd(OAc)2/PPh₃/CuI catalyst 作用下， 以 further solvent(s) 为溶剂， 以31%的产率得到6-ethynylferrocene-2,11-dithia[3.3]orthocyclophane
  参考文献：
  名称：

  Ferrocene substituted thiacyclophanes: Synthesis, electrochemistry and structure of 6-ethynylferrocene-2,11-dithia[3.3]orthocyclophane

  摘要：

  6-Ethynylferrocene-2,11-dithia[3.3]orthocyclophane has been prepared by cross-coupling 6-bromo-2,11-dithia[3.3]orthocyclophane to ethynylferrocene under Sonogashira conditions. The dynamic structure in solution of this potential ligand has been examined by variable temperature NMR whereas its solid state structure has been determined by X-ray diffraction studies. The electrochemical parameters of this cyclophane have also been examined. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.05.029