trans-ruthenium-bis(2-quinaldinate)-bis(triphenylphosphine) | 151436-53-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-ruthenium-bis(2-quinaldinate)-bis(triphenylphosphine)
• CAS: 151436-53-2
• 化学式: C₅₆H₄₂N₂O₄P₂Ru
• 分子量: 969.978
• InChiKey: KPZILUZXNVAJHS-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  cis-ruthenium-bis(2-quinaldinate)-bis(triphenylphosphine)*acetone 以 not given 为溶剂， 生成 trans-ruthenium-bis(2-quinaldinate)-bis(triphenylphosphine)
  参考文献：
  名称：

  Synthesis and crystal structure of a ruthenium complex containing two monodentate DPPM ligands (DPPM = bis(diphenylphosphino)methane)

  摘要：

  The compounds trans-Ru(quin)2(dppm)2 and cis- and trans-Ru(quin)2(PPh3)2 (quin=2-quinaldinate anion; dppm=bis(diphenylphosphino)methane) have been prepared by the reaction of RuCl3.3H2O and Hquin, in basic alcoholic medium, in the presence of dppm and PPh3, respectively. The compounds are characterized by elemental analysis, IR, H-1 and P-31{H-1} NMR spectroscopy. The structure of trans-Ru(quin)2(dppm)2.2MeOH has been determined by X-ray crystallography. The compound has two bidentate N,O-quinaldinate and two monodentate dppm ligands in a trans-N, trans-O, trans-P arrangement.

  DOI：

  10.1016/s0020-1693(00)84989-0