| 220712-59-4

• 分子结构分类: 有机化合物 - 苯类化合物
• CAS: 220712-59-4
• 化学式: C₂₁H₂₆MnN₃O₃
• 分子量: 423.394
• InChiKey: BBKHCCJUGDMPFR-ABNKHVFASA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 C.I.酸性橙108 在 KOH 作用下， 以 甲醇 为溶剂， 以49%的产率得到
  参考文献：
  名称：

  Synthesis, characterisation, reactivity and X-ray crystal structure of a mixed-ligand η1-salicylaldehyde complex of Mn (III)

  摘要：

  A tridentate ligand L has been synthesised from salicylaldehyde and 1-dimethylamino-2-propylamine. It undergoes partial hydrolysis to regenerate salicylaldehyde in methanolic KOH solution. Reaction of manganese(II) acetate with this solution, followed by addition of sodium thiocyanate; produces a dark brown complex [Mn(L)(NCS){o-(CHO)C6H4O}] (1), which has been crystallographically characterised. Coordination of Mn is Jahn-Teller distorted octahedral by L, salicylaldehyde, and thiocyanate. The coordinated aldehyde group reacts with 2-aminoethanol and with 2-aminophenol to give mononuclear neutral Mn(III) complexes 2 and 3, respectively, with mixed Schiff-base ligands, [Mn(L)(L')]. Complexes 1 and 2 are high-spin, while 3 is low-spin. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00285-x