carbanide;ethoxymethanedithioate;palladium(2+);triphenylphosphane | 191533-95-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: carbanide;ethoxymethanedithioate;palladium(2+);triphenylphosphane
• CAS: 191533-95-6
• 化学式: C₂₂H₂₃OPPdS₂
• 分子量: 504.95
• InChiKey: ZHWGMZCDTYOPNZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二-μ-氯二甲基双(三苯基膦)二钯 、 potassium ethyl xanthogenate 以 乙醇 、 苯 为溶剂， 生成 carbanide;ethoxymethanedithioate;palladium(2+);triphenylphosphane
  参考文献：
  名称：

  Synthesis and characterization of methylpalladium(II) dithiolate complexes of the type [PdMe(S⌢S)(ER3)] (S⌢S = S2CNR 2, S2COEt, S2P(OR)2, S2 PPh2; ER3 = PMePh2, PPh3, AsPh3)

  摘要：

  Methylpalladium(II) dithiolate complexes of the type [PdMe(S ( ) over cap S)(ER3)] (S ( ) over cap S = S2CNR2 (R = Me or Et), S2COEt, S2P(OR)(2) (R = Et, Pr-n, Pr-1), S2PPh2; ER3 = PMePh2, PPh3, AsPh3) have been synthesized by the reaction of [Pd2Me2(mu-Cl)(2)(PMePh2)(2)] with sodium/potassium/ammonium salts of the dithio acid or by treatment of [PdMeCl(cod)] with ER3 followed by sodium/potassium/ammonium salts of the dithio ligand. All the complexes were characterized by elemental analysis, LR and nuclear magnetic resonance (H-1, (31)p) data.

  DOI：

  10.1016/s0022-328x(96)06619-3