4,4'-(1-甲基戊亚基)双酚 | 14007-30-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4,4'-(1-甲基戊亚基)双酚
• 中文别名: 4,4'-(1-甲代亚戊基)二苯酚
• 英文名称: 2,2-bis-(4-hydroxyphenyl)-hexane
• 英文别名: 2,2-bis(p-hydroxyphenyl)hexane；2,2-bis-(4-hydroxy-phenyl)-hexane；2,2-Bis-(4-hydroxy-phenyl)-hexan；4,4'-(1-methylpentylidene)bisphenol；2,2-bis(4-hydroxy phenyl)hexane；2,2-bis(4-hydroxyphenyl)hexane；4,4/'-(1-Methylpentylidene)bisphenol；4-[2-(4-hydroxyphenyl)hexan-2-yl]phenol
• CAS: 14007-30-8
• 化学式: C₁₈H₂₂O₂
• 分子量: 270.371
• InChiKey: ZQTPHEAGPRFALE-UHFFFAOYSA-N

物化性质

• 沸点：
  210 °C(Press: 0.5 Torr)
• 密度：
  1.085±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4,4'-(1-甲基戊亚基)双酚 生成 2,2-bis-(4-benzoyloxy-phenyl)-hexane
  参考文献：
  名称：

  The Relation of Estrogenic Activity to Structure in Some 4,4'-Dihydroxydiphenylmethanes¹

  摘要：

  DOI：

  10.1021/ja01234a038
• 作为产物：
  描述：

  2-己酮 、 苯酚 在 盐酸 作用下， 生成 4,4'-(1-甲基戊亚基)双酚
  参考文献：
  名称：

  Campbell, Proceedings of the Royal Society of London. Series B, Biological sciences, 1940, vol. 129, p. 528,537

  摘要：

  DOI：

文献信息

• Process for producing polycarbonate oligomer and process for producing polycarbonate resin from the same
  申请人：——

  公开号：US20040162439A1

  公开（公告）日：2004-08-19

  A process for producing an aromatic polycarbonate oligomer according to an interfacial polymerization method comprising reacting an aqueous solution of a bisphenol compound and phosgene in the presence of an organic solvent in a reactor, removing reaction heat by cooling, utilizing vaporization latent heat of the organic solvent to be used, cooling vaporized organic solvent through a condenser and returning an exhaust gas from the condenser to the reactor and a process for producing an aromatic polycarbonate resin used the same.

  根据界面聚合法生产芳香族聚碳酸酯寡聚物的过程，包括在反应器中将双酚化合物的水溶液与光气在有机溶剂的存在下进行反应，通过冷却来移除反应热，利用所用有机溶剂的蒸发潜热，通过冷凝器冷却蒸发的有机溶剂，并将冷凝器的排气返回到反应器中，以及使用相同方法生产芳香族聚碳酸酯树脂的过程。
• RECORDING MATERIAL PRODUCED USING NON-PHENOL COMPOUND
  申请人：NIPPON SODA CO., LTD.

  公开号：US20150284321A1

  公开（公告）日：2015-10-08

  An object of the present invention is to provide a recording material or a recording sheet using, as a color-developing agent, a non-phenol compound that is a safe compound in no danger of corresponding to an endocrine disruptor and is good in color developing performance. The non-phenol compound used in the present invention is at least one selected from the group consisting of compounds represented by the following formulas (I) to (III).

  本发明的目的是提供一种使用非酚类化合物作为显色剂的记录材料或记录纸，该非酚类化合物是一种安全化合物，不会对应到内分泌干扰物，并且在显色性能方面表现良好。本发明中使用的非酚类化合物至少选自以下化合物所代表的化合物组，其化学式为(I)至(III)。
• Optically active compound and photosensitive resin composition
  申请人：——

  公开号：US20030211421A1

  公开（公告）日：2003-11-13

  A photoactive compound is used in combination with a photosensitizer, represented by the following formula (1): A −[( J ) m −( X-Pro )] n (1) wherein A represents a hydrophobic unit comprising at least one kind of hydrophobic groups selected from a hydrocarbon group and a heterocyclic group, J represents a connecting group, X-Pro represents a hydrophilic group protected by a protective group Pro which is removable by light exposure, m represents 0 or 1, and n represents an integer of not less than 1. The protective group Pro may be removable by light exposure in association with the photosensitizer (especially, a photo acid generator), or may be a hydrophobic protective group. The hydrophilic group may be a hydroxyl group or a carboxyl group. The photoactive compound has high sensitivity to a light source of short wavelength beams, for resist application, therefore, the photoactive compound is advantageously used for forming a pattern with high resolution.

  一种光活性化合物与光敏剂结合使用，由以下公式（1）表示： A −[( J ) m −( X-Pro )] n (1) 其中，A代表至少包括一种从烃基和杂环基中选择的疏水基的疏水单元，J代表连接基团，X-Pro代表由光照可去除的保护基团Pro保护的亲水基团，m代表0或1，n代表不少于1的整数。 保护基团Pro可以与光敏剂（特别是光酸发生剂）一起通过光照可去除，也可以是疏水保护基团。亲水基团可以是羟基或羧基。光活性化合物对短波长光源具有很高的敏感性，用于光刻应用，因此，该光活性化合物有利于形成具有高分辨率的图案。
• METHOD FOR PRODUCING CYANOGEN-HALIDE, CYANATE ESTER COMPOUND AND METHOD FOR PRODUCING THE SAME, AND RESIN COMPOSITION
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20150299110A1

  公开（公告）日：2015-10-22

  A method for efficiently producing a cyanogen halide with suppressed side effects, and a method for producing a high-purity cyanate ester compound at a high yield includes contacting a halogen molecule with an aqueous solution containing hydrogen cyanide and/or a metal cyanide, so that the hydrogen cyanide and/or the metal cyanide is allowed to react with the halogen molecule in the reaction solution to obtain the cyanogen halide, wherein more than 1 mole of the hydrogen cyanide or the metal cyanide is used based on 1 mole of the halogen molecule, and when an amount of substance of an unreacted hydrogen cyanide or an unreacted metal cyanide is defined as mole (A) and an amount of substance of the generated cyanogen halide is defined as mole (B), the reaction is terminated in a state in which (A):(A)+(B) is between 0.00009:1 and 0.2:1.

  一种用于高效生产抑制副作用的氰卤化物，以及以高收率生产高纯度氰酸酯化合物的方法包括将卤素分子与含有氢氰酸和/或金属氰化物的水溶液接触，使得氢氰酸和/或金属氰化物与卤素分子在反应溶液中发生反应以获得氰卤化物，其中基于1摩尔卤素分子使用超过1摩尔的氢氰酸或金属氰化物，当未反应的氢氰酸或未反应的金属氰化物的物质量定义为摩尔(A)，生成的氰卤化物的物质量定义为摩尔(B)，反应在(A)：(A)+(B)介于0.00009:1和0.2:1之间的状态中终止。
• IONICALLY BONDED SALT HAVING REACTIVE GROUP AND THERMOPLASTIC RESIN COMPOSITION CONTAINING SAME
  申请人：NIPPON NYUKAZAI CO., LTD.

  公开号：US20150166474A1

  公开（公告）日：2015-06-18

  [Problem] Provided are an ionically bonded salt having a reactive group which improves the weather resistance of a thermoplastic resin, and a thermoplastic resin composition containing the ionically bonded salt. [Solution] An ionically bonded salt which has a reactive group and is represented by the following Chemical Formula (1) or the following Chemical Formula (2): in Chemical Formulas (1) and (2) above, R 1 and R 2 each independently represent a substituted or unsubstituted linear, branched, or cyclic alkyl group having from 1 to 30 carbon atoms, a substituted or unsubstituted aryl group having from 6 to 30 carbon atoms, or a substituted or unsubstituted arylalkyl group having from 7 to 31 carbon atoms, A is a linear or branched alkylene group having from 2 to 4 carbon atoms, n represents an integer of 0 to 50, and Q1 and Q2 each independently represent at least one kind selected from the group consisting of an ammonium ion having an ethylenically unsaturated bond, an imidazolium ion having an ethylenically unsaturated bond, a pyridinium ion having an ethylenically unsaturated bond, a pyrrolidinium ion having an ethylenically unsaturated bond, a pyrrolinium ion having an ethylenically unsaturated bond, a piperidinium ion having an ethylenically unsaturated bond, a pyrazinium ion having an ethylenically unsaturated bond, a pyrimidinium ion having an ethylenically unsaturated bond, a triazolium ion having an ethylenically unsaturated bond, a triazinium ion having an ethylenically unsaturated bond, a quinolinium ion having an ethylenically unsaturated bond, an isoquinolinium ion having an ethylenically unsaturated bond, an indolinium ion having an ethylenically unsaturated bond, a quinoxalinium ion having an ethylenically unsaturated bond, a piperazinium ion having an ethylenically unsaturated bond, an oxazolinium ion having an ethylenically unsaturated bond, a thiazolinium ion having an ethylenically unsaturated bond, and a morpholinium ion having an ethylenically unsaturated bond.

  提供了一种离子键合盐，具有改善热塑性树脂的耐候性的反应性基团，以及含有该离子键合盐的热塑性树脂组合物。具有以下化学式（1）或以下化学式（2）表示的具有反应性基团的离子键合盐： 在上述化学式（1）和（2）中，R1和R2分别独立表示具有1至30个碳原子的取代或未取代的直链、支链或环烷基基团，具有6至30个碳原子的取代或未取代芳基基团，或具有7至31个碳原子的取代或未取代芳基烷基基团，A表示具有2至4个碳原子的直链或支链烷基基团，n表示0至50的整数，Q1和Q2分别独立表示从具有乙烯不饱和键的氨基离子、具有乙烯不饱和键的咪唑离子、具有乙烯不饱和键的吡啶离子、具有乙烯不饱和键的吡咯烷离子、具有乙烯不饱和键的吡咯离子、具有乙烯不饱和键的哌啶离子、具有乙烯不饱和键的吡嗪离子、具有乙烯不饱和键的嘧啶离子、具有乙烯不饱和键的三唑离子、具有乙烯不饱和键的三唑离子、具有乙烯不饱和键的喹啉离子、具有乙烯不饱和键的异喹啉离子、具有乙烯不饱和键的吲哚啉离子、具有乙烯不饱和键的喹啉啉离子、具有乙烯不饱和键的哌啶啉离子、具有乙烯不饱和键的噁唑啉离子、具有乙烯不饱和键的噻唑啉离子和具有乙烯不饱和键的吗啉啉离子中选择的至少一种的群组。