[Pb(2,2'-bipyridine)(NO3)2(H2O)] | 1155308-12-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Pb(2,2'-bipyridine)(NO3)2(H2O)]
• CAS: 1155308-12-5；1318779-19-9；142547-96-4
• 化学式: C₁₀H₁₀N₄O₇Pb
• 分子量: 505.412
• InChiKey: ODPHMGULGUJLRV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 lead(II) nitrate 、 水 在 NaOH 作用下， 以 乙醇 、 水 为溶剂， 生成 [Pb(2,2'-bipyridine)(NO3)2(H2O)]
  参考文献：
  名称：

  Synthesis and molecular characterization of the coordination polymer [Pb(2,2′-Bipy)(NO3)2(H2O)] n

  摘要：

  A new coordination polymer [Pb(2,2'-Bipy)(NO3)(2)(H2O)] (n) has been successfully synthesized and characterized (where 2,2'-Bipy = 2,2'-bipyridine). The crystal structure of the polymer was determined by single-crystal X-ray diffraction, crystallizing in the monoclinic crystal system, space group P2(1)/n with unit cell parameters: a = 7.1673(5), b = 9.8706(6), c = 19.1825(12) ; beta = 90.0780(10)A degrees; V = 1357.08(15) (3), and Z = 16. The Pb atom was six-coordinated with N(1) and N(2) from 2,2'-Bipy, O(2), O(3), and O(6) in nitrate; O(1) from coordinated water, forming a slightly distorted octahedral geometry. The structure units aggregate together to give birth to the infinite 1D chains via bridged nitrate, and 2D networks and three-dimensional frameworks were obtained through hydrogen bonding and pi-pi-stacking interaction among aromatic rings, respectively.

  DOI：

  10.1134/s1070328411030043