| 144718-12-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 144718-12-7
• 化学式: C₁₃H₁₃Cl₂MnN₅
• 分子量: 365.124
• InChiKey: KNDGJICAHJXDQF-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  2,6-bis((1H-pyrazol-1-yl)methyl)pyridine 、 manganese(II) chloride tetrahydrate 以 乙醇 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Consequences of electronic/steric effects on monochelate and bischelate manganese(II) (S = ) complexes using pyridinylpyrazole ligands. Synthesis and electrochemistry

  摘要：

  A group of three high-spin manganese(II) bis-chelates were synthesized using tridentate 2,6-bis(pyrazol-1-ylmethyl)pyridine and its methyl substituted derivatives. The complexes were isolated as crystalline diperchlorate salts. Two five-coordinate mono-chelates with two chlorides as co-ligands were also synthesized. All the complexes were characterized using conventional physico-chemical techniques. Nucleophilic halide displacement reactions in water on the dichloro complexes afforded aqua complexes. When examined by cyclic voltammetry each complex displays an irreversible Mn(III)/Mn(II) couple. The trends in the anodic peak potentials are rationalized on the basis of electronic/steric effects of the methyl groups present near the donor site.

  DOI：

  10.1016/s0277-5387(00)83160-5