Isocinchomeronsaeure | 6011-85-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Isocinchomeronsaeure
• 英文别名: 2,5-pyridinedicarboxylic acid monohydrate；Pyridine-2,5-dicarboxylic acid;hydrate
• CAS: 6011-85-4
• 化学式: C₇H₅NO₄*H₂O
• 分子量: 185.136
• InChiKey: XKIRSCIKZXZRPB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.35
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  88.5
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  vanadia 、 Isocinchomeronsaeure 在 KOH 、 H₂O₂ 作用下， 以 水 为溶剂， 以93%的产率得到K3[VO(O2)2(2,5-pyridinedicarboxylato)] * 2H2O
  参考文献：
  名称：

  Bisperoxovanadium compounds: synthesis and reactivity of some insulin mimetic complexes

  摘要：

  A series of bisperoxovanadium complexes (bpV) of the general formula K-3[VO(O-2)(2)(L-L')] bas been prepared and characterized, where L-L' is a pyridinedicarboxylate (2,3-pdc, 2,4-pdc, 2,5-pdc) or 3-acetatoxypicolinate (3-acetpic). Two structures have been determined: bpV(2,4-pdc), P2(1), a = 7.1018(12) Angstrom, b = 38.187(5) Angstrom, c = 11.4058(8) Angstrom, beta = 90.546(9)degrees, V = 3093.8(7) Angstrom(3), Z = 8, R/R(w) = 0.049/0.055, and bpV(3-acetpic), , a = 7.4037(13) Angstrom, b = 10.709(3) Angstrom, c = 10.9569(19) Angstrom, alpha = 110.742(16)degrees, beta = 95.600(19)degrees, gamma = 100.195(19)degrees, V = 787.4(3) Angstrom(3), Z = 2, R/R(w) = 0.036/0.026. The oxygen atom of the 2-carboxylate group and the oxo ligand are situated in apical positions of a pseudotrigonal plane formed by the nitrogen atom and the centres of the two peroxo groups. The compounds rapidly oxidize sodium tris(3-sulfonatophenyl)phosphine, in water, to the corresponding oxide. The results are discussed with reference to the reported insulin mimetic activity of this class of compounds.

  DOI：

  10.1016/0020-1693(94)04252-q

文献信息

• LIGHT-DIFFUSING FILM
  申请人：Hitachi Chemical Company, Ltd.

  公开号：EP2530517A1

  公开（公告）日：2012-12-05

  Disclosed is a light control film comprising: two of transparent conductive resin substrates each having a transparent conductive layer and a transparent resin substrate; and a light control layer interposed between the two transparent conductive resin substrates to be in contact with the transparent conductive layer sides, the light control layer containing: a resin matrix; and a light control suspension dispersed in the resin matrix, wherein the transparent conductive layer contains: an organic binder resin; and a conductive polymer. The present invention can provide a light control film having satisfactory adhesiveness between the light control layer and the transparent conductive layer and having excellent radio wave transparency.

  本发明公开了一种光控膜，包括：两块透明导电树脂基板，每块基板都有一个透明导电层和一个透明树脂基板；以及一个光控层，该光控层插在两块透明导电树脂基板之间，与透明导电层两侧接触，光控层包含：树脂基体；以及分散在树脂基体中的光控悬浮液，其中透明导电层包含：有机粘合剂树脂；以及导电聚合物。本发明可以提供一种光控膜，其光控层和透明导电层之间的粘合性令人满意，并且具有出色的无线电波透明度。
• Odyakov, Russian Journal of Inorganic Chemistry, 1999, vol. 44, # 2, p. 178 - 182
  作者：Odyakov

  DOI：——

  日期：——
• LIGHT CONTROL FILM
  申请人：Nomura Satoyuki

  公开号：US20120314276A1

  公开（公告）日：2012-12-13

  Disclosed is a light control film comprising: two of transparent conductive resin substrates each having a transparent conductive layer and a transparent resin substrate; and a light control layer interposed between the two transparent conductive resin substrates to be in contact with the transparent conductive layer sides, the light control layer containing: a resin matrix; and a light control suspension dispersed in the resin matrix, wherein the transparent conductive layer contains: an organic binder resin; and a conductive polymer. The present invention can provide a light control film having satisfactory adhesiveness between the light control layer and the transparent conductive layer and having excellent radio wave transparency.
• US4093622A
  申请人：——

  公开号：US4093622A

  公开（公告）日：1978-06-06
• US8570642B2
  申请人：——

  公开号：US8570642B2

  公开（公告）日：2013-10-29