1-benzyl-3-phenyldiaziridine | 41316-33-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-benzyl-3-phenyldiaziridine
• 英文别名: 1-Benzyl-3-phenyldiaziridin
• CAS: 41316-33-0
• 化学式: C₁₄H₁₄N₂
• 分子量: 210.279
• InChiKey: VORLVMDBGLJNPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  25
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-(2-(hepta-1,3-diyn-1-yl)phenyl)-4,4-dimethylpent-2-yn-1-one 、 1-benzyl-3-phenyldiaziridine 以 苯 为溶剂， 以38%的产率得到(1-benzyl-2-benzylidenehydrazineyl)-1-(tert-butyl)-2-propyl-9H-fluoren-9-one
  参考文献：
  名称：

  二氮丙啶与苯并nes的反应得到N-芳基hydr。

  摘要：

  报道了热生成的苯并炔与二氮丙啶的反应。这些捕获反应遵循的路径与Heine及其同事与电子不足的炔烃先前报道的相同。一步有效地获得了所得的N-芳基hydr。亲核重氮基氮原子向亲电子性更高的苯炔碳上加成模式的偏爱与基于畸变分析所预测的一致。证明了将the转化为Fisher-吲哚加合物的可行性。

  DOI：

  10.1021/acs.orglett.8b03439

文献信息

• [EN] MULTI-COMPONENT HOST MATERIAL AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME<br/>[FR] MATÉRIAU HÔTE À CONSTITUANTS MULTIPLES ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LE COMPRENANT
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2015174738A1

  公开（公告）日：2015-11-19

  The present invention relates to an organic electroluminescent device comprising at least one light-emitting layer between an anode and a cathode, wherein the light-emitting layer comprises a host and a dopant; the host consists of multi-component host compounds; at least a first host compound of the multi-component host compounds is a specific bicarbazole derivative containing an aryl group, and a second host compound is a specific carbazole derivative including a nitrogen-containing heteroaryl group. According to the present invention, an organic electroluminescent device using the multi-component host compounds has a high efficiency and long lifespan compared to the conventional organic electroluminescent device using one component of a host.
• [EN] MULTI-COMPONENT HOST MATERIAL AND AN ORGANIC ELECTROLUMINESCENCE DEVICE COMPRISING THE SAME<br/>[FR] MATÉRIAU HÔTE MULTI-COMPOSANT ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LE CONTENANT
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2015178732A1

  公开（公告）日：2015-11-26

  The present invention relates to a multi-component host material and an organic electroluminescent device comprising the same. By comprising a specific combination of the multi-component host compounds, the organic electroluminescent device according to the present invention can provide high luminous efficiency and excellent lifespan characteristics.