4,4'-磺酰基双(N,N-双(4-(叔丁基)苯基)苯胺) | 1396165-17-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 4,4'-磺酰基双(N,N-双(4-(叔丁基)苯基)苯胺)
• 英文名称: bis(p-(di-p-tert-butylphenylamino)phenyl)sulfone
• 英文别名: bis{4-[bis(4-tert-butylphenyl)amine]phenyl} sulfone；4,4'-Sulfonylbis(N,N-bis(4-(tert-butyl)phenyl)aniline)；4-tert-butyl-N-[4-[4-(4-tert-butyl-N-(4-tert-butylphenyl)anilino)phenyl]sulfonylphenyl]-N-(4-tert-butylphenyl)aniline
• CAS: 1396165-17-5
• 化学式: C₅₂H₆₀N₂O₂S
• 分子量: 777.127
• InChiKey: KLVFTGCIKWMZLS-UHFFFAOYSA-N

物化性质

• 沸点：
  826.7±65.0 °C(Predicted)
• 密度：
  1.099±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  15.9
• 重原子数：
  57
• 可旋转键数：
  12
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  49
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4,4'-二氟二苯砜 、 二(4-叔丁基苯基)胺 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 1.5h， 以77%的产率得到4,4'-磺酰基双(N,N-双(4-(叔丁基)苯基)苯胺)
  参考文献：
  名称：

  用于纯蓝色有机发光二极管的高效热激活延迟荧光材料的设计

  摘要：

  咔唑/砜衍生物在溶液和掺杂薄膜中都具有高效的热激活延迟荧光 (TADF) 的特征。基于该化合物的纯蓝色有机发光二极管 (OLED) 在低电流密度下表现出非常高的外量子效率 (EQE)，接近 10%。由于 TADF 仅发生在以供体和受体为中心的 (3)ππ* 状态接近或高于三重分子内电荷转移 ((3)CT) 状态的双极系统中，因此控制供体和受体的 π 共轭长度被认为与在蓝色 TADF 材料设计中打破它们之间的 π 共轭一样重要。

  DOI：

  10.1021/ja306538w

文献信息

• ORGANIC MIXTURE AND APPLICATION THEREOF IN ORGANIC ELECTRONIC DEVICES
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20200317646A1

  公开（公告）日：2020-10-08

  The present invention relates to an organic mixture and an application thereof in organic electronic devices. The organic mixture comprises a spirofluorene organic compound containing a fused heterocyclic ring and an aromatic fused heterocyclic organic compound containing an electron-donating group. A combination of the two materials may be used as a host material of a phosphorescent organic light-emitting diode (OLED), which may use the energy of excitons and balance the charge transport to the greatest extent and which may effectively reduce the concentration of excitons and the operating voltage of a corresponding device, thereby effectively improving the efficiency and service life of the related electronic device in order to provide an effective solution for improving the overall performance of an organic electronic device.

  本发明涉及一种有机混合物及其在有机电子器件中的应用。该有机混合物包括含有螺环异芳烃环的螺芴有机化合物和含有供电子给体基团的芳香融合杂环有机化合物。这两种材料的组合可用作磷光有机发光二极管（OLED）的主体材料，该二极管可以利用激子的能量并最大程度地平衡电荷传输，从而有效降低激子的浓度和相应器件的工作电压，从而有效提高相关电子器件的效率和使用寿命，为改善有机电子器件的整体性能提供有效解决方案。
• 발광 재료 및 유기 발광 소자
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION 고쿠리쓰다이가쿠호진 규슈다이가쿠(520070190503)

  公开号：KR20150016242A

  公开（公告）日：2015-02-11

  하기 일반식으로 나타내는 화합물을 발광층에 갖는 유기 발광 소자는 발광 효율이 높다. 하기 일반식의 R ∼ R 은 수소 원자 또는 치환기를 나타내지만, R ∼ R 중 적어도 1 개는 아릴기, 디아릴아미노기 또는 9-카르바졸릴기이다.

  具有发光层的有机发光器件具有高发光效率。其中一般式中的R ∼ R表示氢原子或取代基，但至少其中的一个是芳基、二芳基氨基或9-羰基。
• ORGANOMETALLIC COMPLEX AND APPLICATION THEREOF IN ELECTRONIC DEVICES
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20190241590A1

  公开（公告）日：2019-08-08

  Disclosed are an organometallic complex comprising a new six-membered N-heterocyclic ligand, and an application thereof in an organic electronic device, especially in a phosphorescent organic light-emitting diode. The present invention further relates to an organic electronic device comprising the organometallic complex according to the present invention, especially an organic light-emitting diode, and an application thereof in display and illumination technology. In the present invention, the device structure is optimized and the concentration of the metal complex in the substrate is changed, so that the device achieves the optimal performance, and an OLED device having high efficiency, high luminance and high stability is achieved, thereby providing a better choice of materials for full-colour display and illumination application.

  揭示了一种含有新的六元N-杂环配体的有机金属络合物，以及其在有机电子器件中的应用，特别是在磷光有机发光二极管中的应用。本发明还涉及一种含有根据本发明的有机金属络合物的有机电子器件，特别是有机发光二极管，以及其在显示和照明技术中的应用。在本发明中，优化了器件结构并改变了基板中金属络合物的浓度，使得器件实现了最佳性能，并实现了具有高效率、高亮度和高稳定性的OLED器件，从而为全彩显示和照明应用提供了更好的材料选择。
• Organic-electroluminescent-element material and organic electroluminescent element using same
  申请人：NIPPON STEEL & SUMIKIN CHEMICAL CO., LTD.

  公开号：US10446767B2

  公开（公告）日：2019-10-15

  Disclosed is an organic electroluminescent device (organic EL device) that is improved in luminous efficiency, sufficiently secures driving stability, and has a simple construction. The device is an organic electroluminescent device having organic layers including a light-emitting layer between an anode and a cathode laminated on a substrate, in which a carborane compound is incorporated into at least one layer of the organic layers, or is incorporated as a host material into a light-emitting layer containing a phosphorescent light-emitting dopant and the host material. The carborane compound has a structure in which a N-containing fused aromatic ring is bonded to a carborane ring. The N-containing fused aromatic ring is a quinoline ring or has a structure obtained by substituting 1 to 3 ring-forming carbon atoms in a quinoline ring with N atoms.

  本发明公开了一种有机电致发光器件（有机EL器件），其具有提高的发光效率、足够的驱动稳定性和简单的结构。该器件是一种有机电致发光器件，包括在基板上层叠的阳极和阴极之间的有机层，其中至少一个有机层中掺入了碳硼烷化合物，或者将碳硼烷化合物作为宿主材料掺入含有磷光致发光剂和宿主材料的发光层中。碳硼烷化合物具有将含N的融合芳香环连接到碳硼烷环的结构。含N的融合芳香环是喹啉环或通过将喹啉环中1至3个环形碳原子替换为N原子获得的结构。
• Material for organic electroluminescent elements, and organic electroluminescent element using same
  申请人：NIPPON STEEL & SUMIKIN CHEMICAL CO., LTD.

  公开号：US10283721B2

  公开（公告）日：2019-05-07

  Disclosed are an organic electroluminescent device (organic EL device) having improved luminous efficiency, sufficiently secured driving stability, and a simple construction, and a material for an organic EL device. The material for an organic EL device includes a carborane compound having a structure in which at least one carborane ring and at least one dibenzothiophene ring are present, and the at least one carborane ring is bonded to the at least one dibenzothiophene ring at position 1, 2, or 3. In addition, the organic EL device includes, between an anode and a cathode laminated on a substrate, at least one organic layer, in which the at least one organic layer includes the carborane compound.

  揭示了一种具有改善发光效率、充分保证驱动稳定性和简单结构的有机电致发光器件（有机EL器件），以及有机EL器件的材料。用于有机EL器件的材料包括一种碳硼烷化合物，其结构中至少存在一个碳硼烷环和至少一个二苯并噻吩环，且至少一个碳硼烷环与至少一个二苯并噻吩环在1、2或3位置上结合。此外，有机EL器件在衬底上层叠的阳极和阴极之间包括至少一个有机层，其中至少一个有机层包括碳硼烷化合物。