chloro(2,5,8-trithia{9}-o-benzenophane)copper(I) | 152691-21-9

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: chloro(2,5,8-trithia{9}-o-benzenophane)copper(I)
• CAS: 152691-21-9
• 化学式: C₁₂H₁₆ClCuS₃
• 分子量: 355.456
• InChiKey: MFTIXAFGGIPWPV-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  dichloro(2,5,8-trithia{9}-o-benzenophane)copper(II) 以 甲醇 为溶剂， 以20%的产率得到chloro(2,5,8-trithia{9}-o-benzenophane)copper(I)
  参考文献：
  名称：

  Co-ordination of the crown thioether 2,5,8-trithia[9]-o-benzenophane (L¹). Synthesis and crystal structures of [CuL¹(CI)] and [NiL¹₂][BF₄]₂

  摘要：

  The co-ordination abilities of 2,5,8-trithia[9]-o-benzenophane (L1) are compared with several S3-crown macrocycles by structural, spectral and electrochemical techniques. Ligand L1 shows intermediate behaviour relative to the well known ligands 1,4,7-trithiacyclononane and 1,5,9-trithiacyclododecane. The synthesis and characterization of Cu(II), Cu(I), Ni(II) and Co(II) complexes with L1 are carried out. Crystal and molecular structures of two complexes are determined: [CuL1(Cl)], monoclinic, space group P2(1)a, a = 13.562(6), b = 8.046(1), c = 13.770(6) angstrom, beta = 109.96(2)-degrees, Z = 4, R = 0.041 and R' = 0.045; [NiL21][BF4]2, monoclinic, space group P2(1)/c, a = 9.430(2), b = 14.879*2), c = 11.451 (2) angstrom, beta = 11 3.59(1)-degrees, Z = 2, R = 0.058 and R' = 0.057.

  DOI：

  10.1039/dt9930002969