2,4-Dichloro-1-(hex-1-EN-2-YL)benzene | 88374-06-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4-Dichloro-1-(hex-1-EN-2-YL)benzene
• 英文别名: 2,4-dichloro-1-hex-1-en-2-ylbenzene
• CAS: 88374-06-5
• 化学式: C₁₂H₁₄Cl₂
• 分子量: 229.14
• InChiKey: IYNFWTQAQYZSSW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• Preparation of selected epoxides
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0093526A2

  公开（公告）日：1983-11-09

  A process for the production of epoxides of the formula in which the benzene ring A is substituted with 1 to 3 halogen atoms, which are the same or different, and optionally carries other substituents, and R' is which is the same as or different from the other group or C1-6 alkyl, the process comprising electrolysing the corresponding alkene of the formula (II): in a medium comprising a solvent for the alkene and an aqueous solution of a halogen salt, the solvent/water ratio by weight being greater than unity, the solvent being miscible with water at the solvent/water ratio used and being chemically inert to both the alkene and the free halogen produced from the halogen salt by the electrolysis. The epoxides are useful in the synthesis of fungicidal compounds and certain of the epoxides are novel compounds.

  一种生产式如下环氧化物的工艺 其中苯环 A 被 1 至 3 个相同或不同的卤素原子取代，并可选择带有其他取代基，R'为 与其他基团相同或不同的基团 或 C1-6 烷基，该工艺包括电解相应的式 (II) 烯烃： 在由烯的溶剂和卤素盐的水溶液组成的介质中，溶剂/水的重量比大于一，溶剂在所用的溶剂/水比例下与水混溶，并对烯和电解从卤素盐产生的游离卤素具有化学惰性。 环氧化物可用于合成杀菌化合物，其中某些环氧化物是新型化合物。
• Process for the preparation of compounds with a double carbon to carbon bond by dehydration of the corresponding alcohol
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0235714A1

  公开（公告）日：1987-09-09

  Compounds of the formula are prepared by heating an alcohol with the formula in the presence of an alumina catalyst. In these formulas R is C2-6 alkyl, X is halogen, Ci-5 alkyl, C1-4 alkoxy, halo-C1-4 alkyl, halo-C1-4 alkoxy, nitro, phenyl, phenoxy, benzyl, benzyloxy (optionally ring substituted with halogen), alkylenedioxy, haloalkylenedioxy, amino, mono or di C1-4 alkyl amino, hydroxy, morpholino (and carboxy and alkyl esters thereof), n is an integer having a value of 1, 2 or 3 and when n is 2 or 3 the substituents represented by X are the same or different.

  式化合物 式的醇在氧化铝催化剂存在下加热制备。 的醇在氧化铝催化剂存在下加热制备。 在这些式子中，R 是 C2-6 烷基，X 是卤素、Ci-5 烷基、C1-4 烷氧基、卤代-C1-4 烷基、卤代-C1-4 烷氧基、硝基、苯基、苯氧基、苄基、苄氧基（可选择环状被卤素取代）、亚烷基二氧基、卤代亚烷基二氧基、氨基、单或双 C1-4 烷基氨基、羟基、吗啉基（及其羧基和烷基酯），n 为数值为 1、2 或 3 的整数，当 n 为 2 或 3 时，X 所代表的取代基相同或不同。
• Substituted alkenes and processes for their preparation
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0110536B1

  公开（公告）日：1988-09-21