N,N-dibenzylaminobenzo[d][1,3,2]dithiaphospholane | 1133473-86-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N-dibenzylaminobenzo[d][1,3,2]dithiaphospholane
• CAS: 1133473-86-5
• 化学式: C₂₀H₁₈NPS₂
• 分子量: 367.475
• InChiKey: UNEJLQRMYHEOQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.81
• 重原子数：
  24.0
• 可旋转键数：
  5.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  1,2-苯二硫醇 、 二苄胺 在 三乙胺 、 三氯化磷 作用下， 以 二氯甲烷 为溶剂， 反应 16.5h， 以83%的产率得到N,N-dibenzylaminobenzo[d][1,3,2]dithiaphospholane
  参考文献：
  名称：

  The coordination chemistry and reactivity of amino-dithiaphospholanes with rhodium, iridium, and ruthenium

  摘要：

  Novel amino-dithiaphospholane complexes of ruthenium, iridium, and rhodium were synthesized, and their properties were studied. Reaction of the new amino-dithiaphospholane (RS)(2)PNR2' (R = binaphthyl, R' = CH2Ph, (rac)-4) with [RuCl2(P-cymene)](2) afforded [RuCl2(p-cymene)((rac)-4)] in 67% isolated yield. Similarly, the new amino-dithiaphospholanes (RS)(2)PNR2' (R = cyclohexyl, (rac)-7) and (RS)(2)PNR2' (R = phenyl, 9) gave upon reaction with [RhCl(CO)(2)](2) and [IrCp*Cl-2](2) the novel complexes [RhCl(CO)(L)(2)] and [IrCp*Cl-2(L)] (L = (rac)-7, 9) in 61-96% yields. The ruthenium complex is catalytically active for the etherification of propargylic alcohols with methanol and ethanol (8-48 h, 90 degrees C, 40-85% isolated yields). (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.12.034