{(MoCl3(PhCH2SMe))2(μ-S2)(μ-PhCH2SMe)} | 155342-92-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: {(MoCl3(PhCH2SMe))2(μ-S2)(μ-PhCH2SMe)}
• CAS: 155342-92-0
• 化学式: C₂₄H₃₀Cl₆Mo₂S₅
• 分子量: 883.43
• InChiKey: LEOGUGPFIOLSFI-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  13.08
• 重原子数：
  37.0
• 可旋转键数：
  8.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  、 苄基甲基硫醚 以 二氯甲烷 为溶剂， 以50-60的产率得到{(MoCl3(PhCH2SMe))2(μ-S2)(μ-PhCH2SMe)}
  参考文献：
  名称：

  Disulfur-bridged complexes of molybdenum. Crystal structure of the dimolbdenum(IV) complex [{MoCl₃(C₄H₈S)}₂(µ-S₂)(µ-C₄H₈S)] and of the Mo^IVMo^Vcomplex [(Me₂S)₂Cl₂Mo({µ-S₂)(µ-S)MoCl₃(SMe₂)]

  摘要：

  Treatment of [Mo(CO)6] with S2Cl2 gave a very dark green material of empirical formula Mo2S2Cl6.CH2Cl2 1 which, on reaction with L, gave green [{MoCl3(L)}2(mu-S2)(mu-L)] (L = C4H8S 2a, PhCH2SMe 2b or C4H8O 2c), and with SMe2 gave the novel, brown, unsymmetrical, mixed-oxidation-state complex [(Me2S)2Cl2Mo(mu-S2)(mu-S)MoCl3(SMe2)] 3. The structures of 2a and 3 have been established by X-ray crystallography. Compounds 2a-2c are diamagnetic and NMR data have been obtained, whereas 3 is paramagnetic and shows, in a CH2Cl2 glass at 40 K, a broad, roughly axial EPR resonance with g(max) at 1.94.

  DOI：

  10.1039/dt9940000621