d5-ethyl d5-benzoate | 121339-53-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: d5-ethyl d5-benzoate
• CAS: 121339-53-5
• 化学式: C₉H₁₀O₂
• 分子量: 160.098
• InChiKey: MTZQAGJQAFMTAQ-CFTAVCBPSA-N

反应信息

• 作为反应物：
  描述：

  四氯化钛 、 d5-ethyl d5-benzoate 以 neat (no solvent, gas phase) 为溶剂， 生成
  参考文献：
  名称：

  Fourier transform infrared spectra of three titanium tetrachloride-ethyl benzoate complexes. Assignment based on five isotopic homologues and extension of the ethyl benzoate force field

  摘要：

  FTIR spectra (200-1750 cm-1) are given for (TiCl4EB)2, (TiCl4)2EB and TiCl4EB2, where EB is ethyl benzoate. A full assignment is given for (TiCl4EB)2 based on extension of an ethyl benzoate force field and four isotopically labelled complexes with O-18-carbonyl-EB, d5-EB, Ed5-B and d5-Ed5-B. There is no evidence for bidentate complexation or complexation through the ether oxygen in any of the complexes. A strong coupling between the a-C-O stretching vibration and the ethyl group deformations can make simplified interpretations of differences between spectra misleading.

  DOI：

  10.1016/0584-8539(92)80045-x