| 186131-84-0

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• CAS: 186131-84-0
• 化学式: C₂₇H₂₆N₅RuS₂*ClO₄
• 分子量: 685.19
• InChiKey: KHUWQNFXEBFXQE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  顺-双(2,2-二吡啶)二氯化钌(II) 水合物 、 2-methylamino-1-cyclopentene-1-dithiocarboxylic acid 、 silver perchlorate 以 乙醇 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Studies on some mixed-ligand complexes of ruthenium(II) involving dithiocarboxylates, dithiocarbamates, triphenylphosphine and bipyridine

  摘要：

  Ruthenium(II) complexes [Ru(R-acda)(2)(PPh(3))(2)] (1a-e), [Ru(R-acda)(bpy)(2)](ClO4)(2a-d), [Ru(R-acda)(phen)(2)]ClO4) (2e-g), [Ru(R(2)-dtc)(bpy)(2)] (ClO4) (3a, b) and [Ru(R(2)-dtc) (phen)(2)]ClO4)(3c, d) (where R-acdaH = 2-alkylamino-1-cyclopentene-1-dithicarboxylic acid, R(2)-dtcNa = sodium N,N'-dialkyl dithiocarbamate, bpy = 2,2'-bipyridine and phen = 1,10-phenanthroline) have been synthesized and characterized. The H-1 NMR spectra of the phosphine complexes (1a-e) show that, with the increase in the chain length of the alkyl group of R-acda(-), the N-alkylamino proton becomes more deshielded and is accompanied by a shift of the NH stretching frequency v(NH) to lower energy. A linear relationship is obtained between the chemical shift delta(NH) and v(NH). All the complexes exhibit absorption bands due to d pi --> pi* (bpy, phen or PPh(3)), d pi --> pi* (R-acda(-) or R(2)-dtc(-)) charge transfer transitions and pi --> pi* intraligand transition. Complexes 1a-e undergo two irreversible oxidations, Ru-II --> Ru-III and Ru-III --> Ru-IV, while the other complexes (2, 3) exhibit one reversible (Ru-II/Ru-III) and one irreversible (Ru-III --> Ru-IV) oxidation process. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/s0277-5387(96)00336-1