HgCl((η(5)-C5H5)Fe(η(5)-C5H3CPh=NC6H4OMe-4)) | 158965-28-7

• 英文名称: HgCl((η(5)-C5H5)Fe(η(5)-C5H3CPh=NC6H4OMe-4))
• CAS: 158965-28-7
• 化学式: C₂₄H₂₀ClFeHgNO
• 分子量: 630.319
• InChiKey: NYRYGVNMVUVANX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  tin 、 HgCl((η(5)-C5H5)Fe(η(5)-C5H3CPh=NC6H4OMe-4)) 以 xylene 为溶剂， 以76%的产率得到SnCl2((η(5)-C5H5)Fe(η(5)-C5H3CPh=NC6H4OMe-4))2
  参考文献：
  名称：

  Transmetallation reaction of cyclomercurated anils of benzoylferrocene with metallic tin.

  摘要：

  The transmetallation reaction of cyclomercurated anils of benzoylferrocene [HgCl{(eta(5)-C5H5)Fe(eta(5)-C5H3CPh=NAr)}] (Ar = substituted phenyl groups) with metallic tin was carried out in refluxing xylene to give dichlorobisferrocenyltin(IV) [SnCl2{(eta(5)-C5H5)Fe(eta(5)-C5H3CPh=NAr)}(2)]. The composition and structure of products were characterized by elemental analysis, IR, H-1-NMR and 2D NOESY spectra. The molecular structure of [SnCl2{(eta(5)-C5H5)Fe(eta(5)-C5H3CPh = NC6H4-4-CH3)}2] was determined by single crystal X-ray analysis. The distances of N and Sn are 2.519(3) and 2.501(3) Angstrom, respectively, shorter than the sum of van der Waals radii of N and Sn (3.6 Angstrom), indicating an intramolecular coordination of N and Sn. The Sn-119-NMR spectra were recorded, and a satisfactory linear relationship was found to exist between the Sn-119 shifts (delta) and Hammett substituent constants. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00634-2