2,2'-bis(benzimidazol-1-ylmethyl)-biphenyl | 1181843-35-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2'-bis(benzimidazol-1-ylmethyl)-biphenyl
• CAS: 1181843-35-5
• 化学式: C₂₈H₂₂N₄
• 分子量: 414.509
• InChiKey: CJMNLNAQSWUNEO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.15
• 重原子数：
  32.0
• 可旋转键数：
  5.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  35.64
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  2,2'-bis(benzimidazol-1-ylmethyl)-biphenyl 、 cadmium(II) iodide 以 甲醇 为溶剂， 以51%的产率得到Cd2(2,2'-bis(benzimidazol-1-ylmethyl)-biphenyl)2I4
  参考文献：
  名称：

  Structures, Fluorescent Properties of the d ¹⁰ Metal Ions Compounds Based on Molecular Clips

  摘要：

  Two closed-shell d(10) metal ions complexes Cd-2(L)(2)(I)(4) (1) and Zn-2(L)(2)(Cl)(4)(DMF)2 (2) were prepared from molecular clips, 2,2'-bis(benimidazol-1-ylmethyl)-biphenyl (L), and structurally characterized to investigate the structures. Both compounds 1 and 2 are bimetallic supramolecular rectangles in which two L ligands are connected by two tetrahedral coordinated metal ions. These units are connected together through weak pi center dot center dot center dot pi interaction, and 1 and 2 are crystallized in P2(1)/c and P-1 space group, respectively. Solid state fluorescent measurements exhibit the presence of ligand-based emission at 407 and 370 nm of compounds 1 and 2, respectively.

  DOI：

  10.1080/15533170802293253