| 145638-40-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 145638-40-0
• 化学式: C₁₅H₁₄Cl₂N₂OPdS
• 分子量: 447.681
• InChiKey: MFDDOSUTIANRPS-QIKYXUGXSA-L

反应信息

• 作为产物：
  描述：

  4-methylphenylazo-(2-chloroethylthio)benzene 以 乙醇 、 氯仿 、 水 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and structure of a thioazobenzene palladacycle: Oxygen insertion into the PdC bond by m-chloroperbenzoic acid

  摘要：

  The reaction of p-tolyl-o'-(2-chloroethylthio)azobenzene (LH-1)with Na2PdCl4 affords the complex PdL1Cl, the structure of which has been determined by X-Tay crystallography. The azobenzene ligand acts in the tridentate (C,N,S) fashion and the fourth coordination position is occupied by the chloride ion. In the lattice, the PdL1Cl molecules are present as loose dimers of parallel Pd(C,N,S)Cl units, the Pd ... Pd distance being 3.357(2) angstrom. Reaction of PdL1Cl with m-chloroperbenzoic acid leads to insertion of oxygen into the Pd-C bond to give the corresponding phenolato complex. The insertion reaction is of first order with respect to each of the reactants, and has a large negative entropy of activation. A plausible mechanism is proposed. The structure and properties of PdL1Cl are compared with those of related species.

  DOI：

  10.1016/0022-328x(92)80056-4