| 1111067-06-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1111067-06-1
• 化学式: C₂₆H₂₄AsO₂P
• 分子量: 474.371
• InChiKey: PLBSCZULAWSFMF-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  在 SO₂ 作用下， 以 甲苯 为溶剂， 生成 {manganese(II)(dpaeO2)2(H2O)2(sulfur dioxide)}(perchlorate)2
  参考文献：
  名称：

  Preparation, properties and reactions with sulfur dioxide in the solid state of complexes of the type [Mn(Ph2E(O)YE(O)Ph2)2(H2O)2](ClO4)2 (E=As, P; Y=C2H4, cis-C2H2). The formation of bis-sulfur dioxide complexes which contain both weakly bound and strongly bound sulfur dioxide

  摘要：

  Hexacoordinate manganese(II) perchlorate complexes containing diphosphine dioxide, diarsine dioxide or a mixed phosphine oxide/arsine oxide ligand, [Mn(ligand)2(H2O)2](ClO4)2, react in the solid state with sulfur dioxide to form the [Mn(ligand)2(H2O)2(SO2)2](ClO4)2 adducts, as shown by weight increases. One sulfur dioxide molecule is readily lost on exposure to air, but the second is much more strongly held and is only lost on heating to 65-108-degrees-C. Absorption isotherms have been obtained for the uptake of two molecules of sulfur dioxide by [Mn(dpaeO2)2(H2O)2]ClO4)2 and of one molecule of SO2 by [Mn(dpaeO2)2(H2O)2(SO2)](ClO4)2 (dpaeO2 = Ph2P(O)CH2CH2As(O)Ph2).

  DOI：

  10.1016/s0020-1693(00)82667-5