| 153178-61-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 153178-61-1
• 化学式: C₁₄H₁₆Cl₂N₂Pd
• 分子量: 389.62
• InChiKey: YQUAPWCCBWFZAL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 sodium malonate 、 silver nitrate 以 水 为溶剂， 生成 ((1,2-bis(6-methylpyridin-2-yl)ethane-N,N')-malonato)palladium(II)trihydrate
  参考文献：
  名称：

  Sterically restrictive metal complexes. The synthesis and structural characterization of (1, 2-bis(6-methylpyridin-2-yl)ethane-N,N′)- (malonato)palladium(II) trihydrate. Proton NMR binding studies to cytosine and guanine derivatives

  摘要：

  Two different routes for the preparation of the bidentate ligand 1,2-bis(6-methylpyridin-2-yl)ethane (bmpe) have been explored and are described. 1:1 coordination of this ligand with palladium(II) and the isolation of crystals of the complex as the malonate trihydrate has allowed the crystal and molecular structure to be determined. The compound crystallizes in space group P2(1)/n with a=12.946(1), b=7.431(1), c=20.483(2) angstrom, beta=91.941(3)-degrees, Z=4. The structural analysis reveals that the 6-methyl groups of the bidentate bmpe ligand both project over one side of the square-plane, effectively blocking it off. The interaction of the Pd(bmpe)2+ complex cation with cytosine and guanine derivatives has been investigated by proton NMR spectroscopy.

  DOI：

  10.1016/s0020-1693(00)87539-8
• 作为产物：
  描述：

  二(氰基苯)二氯化钯 、 1,2-bis-(6-methyl-2-pyridyl)ethane 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Sterically restrictive metal complexes. The synthesis and structural characterization of (1, 2-bis(6-methylpyridin-2-yl)ethane-N,N′)- (malonato)palladium(II) trihydrate. Proton NMR binding studies to cytosine and guanine derivatives

  摘要：

  Two different routes for the preparation of the bidentate ligand 1,2-bis(6-methylpyridin-2-yl)ethane (bmpe) have been explored and are described. 1:1 coordination of this ligand with palladium(II) and the isolation of crystals of the complex as the malonate trihydrate has allowed the crystal and molecular structure to be determined. The compound crystallizes in space group P2(1)/n with a=12.946(1), b=7.431(1), c=20.483(2) angstrom, beta=91.941(3)-degrees, Z=4. The structural analysis reveals that the 6-methyl groups of the bidentate bmpe ligand both project over one side of the square-plane, effectively blocking it off. The interaction of the Pd(bmpe)2+ complex cation with cytosine and guanine derivatives has been investigated by proton NMR spectroscopy.

  DOI：

  10.1016/s0020-1693(00)87539-8