| 146546-25-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 146546-25-0
• 化学式: C₆₄H₅₆N₈O₄S₄Zn
• 分子量: 1194.85
• InChiKey: DRENLSBWQKXIPE-NPAISSDASA-L

反应信息

• 作为产物：
  描述：

  zinc(II) acetate dihydrate 、 5,10,15,20-tetrakisporphyrin 以 甲醇 、 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  A porphyrin bearing tetrahydrothiophene pickets; co-ordination behaviour and electron transfer

  摘要：

  A novel 'picket-fence' porphyrin, 5,10,15,20-tetrakis[o-(tetrahydro-2-thenoylamino)phenyl]porphyrin (H-2L) with ligating tetrahydrothiophene rings disposed perpendicular to the porphyrin plane has been synthesised. Its zinc(II) derivative, [ZnL], binds two silver(I) ions co-operatively with a dissociation constant of 4.8 x 10(-8) dm3 mol-1. Time-resolved fluorescence lifetime measurements reveal the presence of intramolecular photoexcited electron transfer in this donor-acceptor system.

  DOI：

  10.1039/dt9920002873