trans-bis(N-methylimidazole)bis(ferrocenecarboxylato)copper(II) | 141823-48-5

• 英文名称: trans-bis(N-methylimidazole)bis(ferrocenecarboxylato)copper(II)
• CAS: 141823-48-5
• 化学式: C₃₀H₃₀CuFe₂N₄O₄
• 分子量: 685.833
• InChiKey: PJFAREHBWJUXJT-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  N-甲基咪唑 、 tetrakis(ferrocenecarboxylato)bis(tetrahydrofuran)dicopper(II)*terahydrofuran 以 甲醇 为溶剂， 生成 trans-bis(N-methylimidazole)bis(ferrocenecarboxylato)copper(II)
  参考文献：
  名称：

  Syntheses and molecular structures of cis and trans monomeric ferrocenecarboxylatocopper(II) complexes with imidazole derivatives

  摘要：

  The products of the reactions of 1,2-dimethylimidazole and N-methylimidazole with tetrakis(ferrocenecarboxylato)dicopper(II) have been isolated and characterized by single-crystal X-ray diffraction. They are the monomeric species cis-bis(1,2-dimethylimidazole)bis(ferrocenecarboxylato)copper(II) 1 and trans-bis(ferrocenecarboxylato)bis(N-methylimidazole)copper(II) 2, respectively. In each complex the copper ion is in a square-planar environment consisting of two imidazole nitrogen atoms and a carboxylate oxygen atom from each ferrocenecarboxylate ligand. The second oxygen atoms of the carboxylate functionalities are involved in weak interactions with the copper ions. The eta-5-C5H4 and eta-5-C5H5 rings of the ferrocenyl moieties are nearly eclipsed with deviations from the eclipsed conformation of 9.7 and 5.5-degrees for 1 and 4.4-degrees for 2.

  DOI：

  10.1039/dt9920001249