{4,5-bis(diphenylphosphanoyl)-octa-N-methyl-1λ5,3λ5-{1,3}diphosphinin-1,1',3,3'-tetraamin-C2,C6}-dichloropalladium | 154787-91-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: {4,5-bis(diphenylphosphanoyl)-octa-N-methyl-1λ5,3λ5-{1,3}diphosphinin-1,1',3,3'-tetraamin-C2,C6}-dichloropalladium
• CAS: 154787-91-4
• 化学式: C₃₆H₄₆Cl₂N₄O₂P₄Pd
• 分子量: 868.008
• InChiKey: BQARDQWQJHLJLM-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  二(氰基苯)二氯化钯 、 4,5-Bis(diphenylphosphanoyl)-octa-N-methyl-1λ⁵,3λ⁵-<1,3>-diphosphinin-1,1',3,3'-tetraamin 以 氯仿 为溶剂， 以52%的产率得到{4,5-bis(diphenylphosphanoyl)-octa-N-methyl-1λ5,3λ5-{1,3}diphosphinin-1,1',3,3'-tetraamin-C2,C6}-dichloropalladium
  参考文献：
  名称：

  o-λ5-[1,3]-Diphosphaphenylen-bis(diphenylphosphanoxid) und sein palladium(ii)-komplex

  摘要：

  4,5-Bis(diphenylphosphanoyl)-octa-N-methyl-1lambda5,3lambda5-[1,3]-diphosphinin-1,1'3,3'-tetraamin (o-lambda5-[1,3]-diphosphaphenylene-bis(diphenyl-phosphanoxide)), 2, is formed from compound 1 by aeration. Compound 2 acts as a chelating ligand owing to the anionic nature of two ylidic carbon atoms in the reaction with (benzonitrile)2PdCl2 to form complex 3. Compound 2 is characterized by its NMR and IR spectra, and compound 3 by the results of an X-ray structural analysis.

  DOI：

  10.1016/0022-328x(93)86057-o