triphenyltin phenylphosphate | 1114945-02-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: triphenyltin phenylphosphate
• CAS: 1114945-02-6
• 化学式: C₄₂H₃₅O₄PSn₂
• 分子量: 872.131
• InChiKey: WOSHVHMFGJLMGD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  6.54
• 重原子数：
  49.0
• 可旋转键数：
  12.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  44.76
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  磷酸单苯酯 、 三苯基氯化锡 在 NaOEt 作用下， 以 乙醇 为溶剂， 以62%的产率得到triphenyltin phenylphosphate
  参考文献：
  名称：

  Self-assembly syntheses and crystal structures of triphenyltin(IV) phenylphosphate: A 1D polymer and a dimer of 24-membered macrocycle

  摘要：

  Two novel organotin(IV) complexes of the types [(Ph3Sn)(4)(O3POPh)(2)](n) 1 and [(Ph(3)Su)(6)(O3POPh)(3)](2) 2 have been prepared by treatment of phenylphosphoric acid and the Ph3SnCl under different conditions. The complexes I and 2 were characterized by elemental analysis, IR and NMR (H-1,C-13,Sn-19) spectroscopy and X-ray crystallography diffraction analysis. The structure analyses reveal that complex I is an infinite ID polymer and complex 2 is a dimer which contains two 24-membered macrocycles. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.07.033