benzyltriphenylammonium cation | 22444-87-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzyltriphenylammonium cation
• 英文别名: Benzyl(triphenyl)azanium
• CAS: 22444-87-7
• 化学式: C₂₅H₂₂N
• 分子量: 336.456
• InChiKey: QUCVNPJIPOQRLJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  镍 、 2-nitroethylene-1,1-dithiol sodium salt 、 benzyltriphenylammonium cation 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Fackler, J. P.; Coucouvanis, D., Chemical Communications (London)

  摘要：

  DOI：

文献信息

• Antistatic and antidust agents, compositions thereof, and methods of manufacture
  申请人：Chowdhury Kumar Sanjoy

  公开号：US20050038274A1

  公开（公告）日：2005-02-17

  A quaternary onium aromatic sulfonate represented by the formula: wherein each R 1 independently comprises substituted or unsubstituted, aliphatic or aromatic, hydrocarbyl, carbocyclic or heterocyclic radicals, each X is selected from the group consisting of phosphorus and nitrogen; wherein “a” has a value of 0, 1 or 2, and “b” has a value of 0 or 1 with the proviso that (a+b) is equal to 1 or 2; G 1 is an aromatic group; E comprises a bis(carbonyloxyalkyl) polydiorganosiloxane, a bis(carbonyloxyaryl) polydiorganosiloxane, and an ether linkage; each Y 1 independently comprises hydrogen, a monovalent hydrocarbon group, alkenyl, allyl, halogen, bromine, chlorine; nitro; and OR, wherein R is a monovalent hydrocarbon group; “q” represents any integer from and including zero through the number of positions on G 1 available for substitution; “t” represents an integer equal to at least one; “s” represents an integer equal to either zero or one; and “u” represents any integer including zero; with the proviso that when E is an ether linkage, then X is phosphorus.

  一种用以下公式表示的四元铵芳基磺酸盐：其中每个R1独立地包括取代或未取代的脂肪或芳香族、烃基、碳环或杂环基团，每个X选自磷和氮组成的群体；其中“a”的值为0、1或2，“b”的值为0或1，但要求(a+b)等于1或2；G1是一个芳香族基团；E包括一种双(羰氧烷基)聚二有机硅氧烷、一种双(羰氧芳基)聚二有机硅氧烷和一种醚键；每个Y1独立地包括氢、一价碳氢化合物基团、烯基、烯丙基、卤素、溴、氯、硝基和OR，其中R是一价碳氢化合物基团；“q”表示从零开始到G1可供取代的位置数的任意整数；“t”表示至少为1的整数；“s”表示为零或一的整数；“u”表示包括零在内的任意整数；但要求当E为醚键时，X为磷。
• Thermoplastic composition containing polymeric anti-static salt, method of making, and use thereof
  申请人：Dean Jennifer

  公开号：US20050140047A1

  公开（公告）日：2005-06-30

  Compositions exhibiting water resistant anti-static properties prepared from a thermoplastic polymer and a polymeric anti-static salt is disclosed.

  本发明公开了一种由热塑性聚合物和聚合性抗静电盐制备的具有耐水抗静电性能的组合物。
• Novel catalytic formulation and its preparation
  申请人：COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH

  公开号：US20030092565A1

  公开（公告）日：2003-05-15

  The present invention describes a generic methodology to formulate a composite solid useful for catalyzing variety of reactions, the present invention in particular relates to a heterogeneous catalyst as a formulation constituting a solid support having deposited thereon a catalytically active material, which is practically insoluble in variety of liquid media, the said insoluble material is constructed from secondary building blocks derived from suitable organometallic active components and the organometallic active component is molecularly modified so as to introduce two or more negatively charged functional groups, these molecularly modified organometallic components upon interaction with salts of Ca 2+ , Sr 2+ and Ba 2+ , provide practically insoluble solid material and the invention further ascertains various ways of formulating organometallic active material on a solid support as a solid catalyst, the methodology is suitable for preparation of wide variety of catalysts having applications in catalyzing diverse reactions in polar and nonpolar reaction media as and the overall integrity of the formulation as a solid material in a liquid phase provides easy catalyst and product separation.

  本发明描述了一种通用方法，用于制备用于催化各种反应的复合固体。本发明特别涉及一种杂质催化剂，作为一种配方构成固体支撑物，其中沉积有催化活性材料，该材料在各种液体介质中实际上不溶。所述不溶材料由适当的有机金属活性组分衍生的次级构建块构成，所述有机金属活性组分经分子修饰，引入两个或更多带负电的功能基团，这些分子修饰的有机金属组分与Ca2+、Sr2+和Ba2+的盐相互作用，提供实际上不溶的固体材料。本发明进一步确定了在固体支撑物上制备有机金属活性材料作为固体催化剂的各种方法，该方法适用于制备广泛应用于极性和非极性反应介质中的各种催化剂，而配方作为液相中的固体材料的整体完整性提供了易于催化剂和产物分离的便利性。
• Antistatic agents and polymer compositions derived therefrom
  申请人：——

  公开号：US20040030015A1

  公开（公告）日：2004-02-12

  An antistatic additive comprises a quaternary onium organosilicon compound having the formula (I) 1 wherein each R 1 independently comprises an aliphatic or aromatic functional groups that may be substituted or unsubstituted; X comprises phosphorus or nitrogen; each R 2 independently comprises an aliphatic or aromatic functional group that may be substituted or unsubstituted; each R 3 independently comprises a hydrogen or an aliphatic or aromatic functional group that may be substituted or unsubstituted; and “n” has a value of about 1 to about 20.

  一种抗静电添加剂，包括具有公式（I）的季铵有机硅化合物，其中每个R1独立地包括可以被取代或未取代的脂肪族或芳香族官能团；X包括磷或氮；每个R2独立地包括可以被取代或未取代的脂肪族或芳香族官能团；每个R3独立地包括氢或可以被取代或未取代的脂肪族或芳香族官能团；“n”的值约为1到20。
• ANTISTATIC AGENTS, COMPOSITIONS THEREOF, AND METHODS OF MANUFACTURE
  申请人：CHOWDHURY Sanjoy Kumar

  公开号：US20090184442A1

  公开（公告）日：2009-07-23

  A quaternary onium aromatic sulfonate represented by the formula: wherein each R 1 independently comprises substituted or unsubstituted, aliphatic or aromatic, hydrocarbyl, carbocyclic or heterocyclic radicals, each X is selected from the group consisting of phosphorus and nitrogen; wherein “a” has a value of 0, 1 or 2, and “b” has a value of 0 or 1 with the proviso that (a+b) is equal to 1 or 2; G 1 is an aromatic group; E comprises a bis(carbonyloxyalkyl) polydiorganosiloxane, a bis(carbonyloxyaryl) polydiorganosiloxane, and an ether linkage; each Y 1 independently comprises hydrogen, a monovalent hydrocarbon group, alkenyl, allyl, halogen, bromine, chlorine; nitro; and OR, wherein R is a monovalent hydrocarbon group.

  一种四元铵芳基磺酸盐，其化学式为：其中每个R1独立地包括取代或未取代的脂肪族或芳香族，烃基，碳环或杂环基团，每个X从磷和氮的群中选择；其中“a”值为0、1或2，“b”值为0或1，但须满足（a+b）等于1或2；G1是芳香基团；E包括一种双（羰基氧基烷基）多二甲基硅氧烷，一种双（羰基氧基芳基）多二甲基硅氧烷和一种醚键；每个Y1独立地包括氢、一价碳氢化合物基团、烯烃、烯丙基、卤素、溴、氯、硝基和OR，其中R是一价碳氢化合物基团。