dibromocopper;2,2,4,4-tetrakis(3,5-dimethylpyrazol-1-yl)-6,6-diphenyl-1,3,5-triaza-2λ5,4λ5,6λ5-triphosphacyclohexa-1,3,5-triene | 164593-72-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dibromocopper;2,2,4,4-tetrakis(3,5-dimethylpyrazol-1-yl)-6,6-diphenyl-1,3,5-triaza-2λ5,4λ5,6λ5-triphosphacyclohexa-1,3,5-triene
• CAS: 164593-72-0
• 化学式: C₃₂H₃₈Br₂CuN₁₁P₃
• 分子量: 893.003
• InChiKey: URTLGHDKUWPGOS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2,4,4-Tetrakis(3,5-dimethylpyrazolyl)-6,6-diphenyl-2λ⁵,4λ⁵,6λ⁵-cyclotriphosphaza-1,3,5-triene 、 copper(ll) bromide 以 二氯甲烷 为溶剂， 以90%的产率得到dibromocopper;2,2,4,4-tetrakis(3,5-dimethylpyrazol-1-yl)-6,6-diphenyl-1,3,5-triaza-2λ5,4λ5,6λ5-triphosphacyclohexa-1,3,5-triene
  参考文献：
  名称：

  Five-coordinate copper(II) complexes of GEM-N3P3Ph2(dmpz)4

  摘要：

  2,2-Diphenyl-4,4,6,6-tetrakis(3,5-dimethyl-1-pyrazolyl)cyclotriphosphazene, N(3)P(3)Ph(2)(dmpz)(4) (2), forms mononuclear five-coordinate complexes N(3)P(3)Ph(2)(dmpz)(4) . CuX(2) [X = Cl (3) and Br (4)] with copper(II) halides. The structure of dichloromethane solvate of the chloro derivative, N(3)P(3)Ph(2)(dmpz)(4) . CuCl2, has been determined by single crystal X-ray diffraction. The metal exists in a distorted trigonal bipyramidal geometry and the ligand 2 acts as an N-3 capping tridentate ligand with two non-geminal pyrazolyl pyridine and one cyclotriphosphazene ring nitrogen and two chloride ions complete the trigonal bipyramidal environment. The spectroscopic (IR, UV-vis and EPR) characterization of the complexes is also reported.

  DOI：

  10.1016/0277-5387(94)00363-j