N-benzyl-2-[(4-methylphenyl)diazenyl]aniline | 869730-63-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-benzyl-2-[(4-methylphenyl)diazenyl]aniline
• CAS: 869730-63-2
• 化学式: C₂₀H₁₉N₃
• 分子量: 301.391
• InChiKey: JZCZELCDVPDMBE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  36.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  sodium tetrachloropalladate(II) 、 N-benzyl-2-[(4-methylphenyl)diazenyl]aniline 以 甲醇 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  A strategy of Pd(II) assisted C–H activation in 2-alkylamino azobenzene ligands: Syntheses, characterisation and structure of a new family of orthopalladated complexes

  摘要：

  Several 2-(arylazo)-N-alkyl aniline ligands, 1a-11a, have been prepared by the reaction between 2-(arylazo) aniline and the appropriate alkyl halide in the presence of K2CO3. Treatment of sodium tetrachloropallaclate with 1a-11a in methanol afforded the orthopalladated complexes 1b-11b, where the ligand is tridentate (C,N,N). The ligands and complexes were characterised from spectroscopic data and confirmed by X-ray studies. The X-ray Structure of 9b displayed an unsupported Pd(II)Pd-...(II) interaction (3.301 angstrom). (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.05.022