| 150179-84-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 150179-84-3
• 化学式: C₁₉H₁₇AsAuCl
• 分子量: 552.685
• InChiKey: UCUCHOLFCPFTSU-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Ylide-gold(I) complexes of the types [Au(ylide)L]+ [Au(ylide)(CCR)] and [Au(ylide){Co(CO)4}]

  摘要：

  Displacement of tetrahydrothiophene (tht) from [Au(ylide)(tht)ClO4 (ylide=CH2PPh3, CH2PPh2Me, CH2PPhMe2, CHPhPPh3, CHMePPh3 or CH2AsPh3) by other neutral or anionic ligands leads to the mono- and dinuclear cationic complexes [Au(ylide)L]ClO4 (L=SbPh3 or phen) or [{Au(ylide)}2(L-L)]ClO4 (L-L=dppm or dpam), complexes with tetracarbonylcobaltate as ligand [Au(ylide){Co(CO)4}] or acetylide complexes [Au(ylide)(C=CR)] (R=Ph or (t)Bu). The structure of [Au(CH2PPhMe2)(phen)]ClO4 was established by single-crystal X-ray diffraction studies.

  DOI：

  10.1016/s0020-1693(00)82880-7