bis(triphenylphosphoranylidene)ammonium bis(benzimidazole-2-thionato)aurate(I) | 159955-99-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 咪唑并吡啶类
• 英文名称: bis(triphenylphosphoranylidene)ammonium bis(benzimidazole-2-thionato)aurate(I)
• CAS: 159955-99-4
• 化学式: C₁₄H₁₀AuN₄S₂*C₃₆H₃₀NP₂
• 分子量: 1033.95
• InChiKey: MJPDEIPZNMLWNQ-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  bis(triphenylphosphine)iminium gold(I) bis(acetylide) 、 1H-苯并咪唑-2-硫醇 以 二氯甲烷 为溶剂， 以81%的产率得到bis(triphenylphosphoranylidene)ammonium bis(benzimidazole-2-thionato)aurate(I)
  参考文献：
  名称：

  Complexes with S-donor ligands. Part 2. Synthesis of anionic bis(thiolato)gold(I) complexes. Crystal structure of [N(PPh₃)₂][Au(SR)₂](R = benzoxazol-2-yl)

  摘要：

  The reaction of [N(PPh3)2][Au(acac)2] (Hacac = acetylacetone) with HSR gave acetylacetone and the complexes [N(PPh3)2][Au(SR)2] [HSR = benzoxazole-2(1H)-thione 1, pyrimidine-2(1H)-thione 2, pyridine-2(1H)-thione 3, 2,3,4,6-tetra-O-acetyl-1-thio-beta-D-glucopyranose 4, 2-thiouracil (2,3-dihydro-2-thioxo-1H-pyrimidin-4-one) 5, 2,3-dihydro-1H-benzimidazole-2-thione 6, 2-thiomalic acid 7, 2-sulfanylethanol 8, D-penicillamine (3-sulfanylvaline) 9]. The crystal structure of 1 has been solved. The gold atom adopts the usual linear co-ordination [175.11 (5)-degrees] and the Au-S bond distances are normal [2.281(2) and 2.283(2) angstrom].

  DOI：

  10.1039/dt9940003183