2-[2-[[2-(2-Pyridin-2-ylethoxymethyl)phenyl]methoxy]ethyl]pyridine | 854372-56-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-[2-[[2-(2-Pyridin-2-ylethoxymethyl)phenyl]methoxy]ethyl]pyridine
• CAS: 854372-56-8
• 化学式: C₂₂H₂₄N₂O₂
• 分子量: 348.445
• InChiKey: AFOXPCGNGJKDOP-UHFFFAOYSA-N

物化性质

• 沸点：
  465.2±40.0 °C(Predicted)
• 密度：
  1.128±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  26
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  44.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-羟乙基吡啶 、 copper(II) perchlorate hexahydrate 、 2-[2-[[2-(2-Pyridin-2-ylethoxymethyl)phenyl]methoxy]ethyl]pyridine 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and characterization of a versatile bis(pyridylether) ligand and its complexes with Ag(I), Cu(II) and Co(II)

  摘要：

  A new bis(pyridylether) ligand L was synthesized in 46% yield from the reaction of two equivalents of 2-pyridylethanol with alpha,alpha'-dibromo-o-xylene in the presence of sodium hydroxide. Ligand L possesses structural features that allow it to react either intermolecularly or in a chelating fashion with transition metal ions. With AgNO3, ligand L forms a helical metallopolymer. Ligand L, in combination with 2-pyridylethanol, reacts with Cu(CIO4)(2) to form a bridged dinuclear complex. With Co(NCS)(2), ligand L behaves as a chelating ligand to give a monomeric octahedral complex. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.02.008