bis[4-methyl-N-(2-(2-pyridyl)ethyl)benzenesulfonamide]nickel(II) | 189447-87-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis[4-methyl-N-(2-(2-pyridyl)ethyl)benzenesulfonamide]nickel(II)
• CAS: 189447-87-8
• 化学式: C₂₈H₃₀N₄NiO₄S₂
• 分子量: 609.393
• InChiKey: XARXGTLKHRRHBN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-methyl-N-(2-(pyridin-2-yl)ethyl)benzenesulfonamide 、 镍 在 Et₄NClO₄ 作用下， 以 乙腈 为溶剂， 生成 bis[4-methyl-N-(2-(2-pyridyl)ethyl)benzenesulfonamide]nickel(II)
  参考文献：
  名称：

  Electrochemical synthesis and crystal structures of bis{4-methyl-N-(2-pyridin-2-yl-ethyl)benzenesulfonamide}copper(II) and bis{4-methyl-N-(2-pyridin-2-yl-ethyl)benzenesulfonamide}nickel(II)

  摘要：

  The complexes [ML(2)] (M = Cu and Ni) were prepared by electrochemical oxidation of the appropriate metal in a solution of 2-(2-pyridyl)-N-tosylethylamine in acetonitrile. The crystal and molecular structures of bis {4-methyl-N-(2-pyridin-2-yl-ethyl)benzenesulfonamide}copper(II) and bis{4-methyl-N-(2-pyridin-2-yl-ethyl)benzenesulfonamide} nickel(II) were determined by X-ray diffraction. Both compounds are isotypical and crystallize in the triclinic space group P1 with one molecule in the unit cell. In both structures the metal atoms are in a distorted square-planar environment defined by two amide and two pyridyl nitrogen atoms. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00465-2