N'-(4'-benzo[15-crown-5])biphenylaminoglyoxime | 807342-33-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N'-(4'-benzo[15-crown-5])biphenylaminoglyoxime
• CAS: 807342-33-2
• 化学式: C₂₈H₃₁N₃O₇
• 分子量: 521.57
• InChiKey: XNCVCWRVBYBPSX-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  copper(II) choride dihydrate 、 N'-(4'-benzo[15-crown-5])biphenylaminoglyoxime 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 以87%的产率得到copper(II)(N'-(4'-benzo[15-crown-5])biphenylaminoglyoxime(1+))2
  参考文献：
  名称：

  Synthesis of N-(4 -Benzo[15-crown-5])biphenylaminoglyoxime and Its Complexes with Some Transition Metals

  摘要：

  N'-(4'-Benzo[15-crown-5])biphenylaminoglyoxime (H2L) and sodium chloride salt of N'-(4'-benzo[15-crown-5])biphenylaminoglyoxime (H2L . NaCl) have been prepared from 4-biphenylchloroglyoxime, 4'-aminobenzo[15-crown-5], and sodium bicarbonate and sodium chloride. Nickel(II), cobalt(II), and copper(II) complexes with H2L and H2L . NaCl have a metal-ligand ratio of 1 : 2 and the ligand coordinates through the two N atoms, as do most of the vic-dioximes. Their IR spectra and elemental analyses are given, together with H-1 NMR spectra of the ligands.

  DOI：

  10.1023/b:ruco.0000034790.13764.b7