FeCl2[2,6-bis(3-mesitylpyrazol-1-yl)pyridine] | 827306-33-2

• 英文名称: FeCl2[2,6-bis(3-mesitylpyrazol-1-yl)pyridine]
• CAS: 827306-33-2
• 化学式: C₂₉H₂₉Cl₂FeN₅
• 分子量: 574.336
• InChiKey: LLBKHDBWEYODBF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  FeCl2[2,6-bis(3-mesitylpyrazol-1-yl)pyridine] 以 四氢呋喃 为溶剂， 以99%的产率得到[Fe(2,6-bis(3-mesitylpyrazol-1-yl)pyridine)2][FeCl4]2
  参考文献：
  名称：

  Iron complexes of terdentate nitrogen ligands: formation and X-ray structure of three new dicationic complexes

  摘要：

  Dicationic iron complexes were obtained upon complexation of the ligands 6,6"-di(p-tolyl)-2,2':6',2"-terpyridine (L-1) or 2,6-bis(3-tnesitylpyrazol-1-yl)pyridine (L-2) with iron dichloride or iron trichloride. They were characterized by X-ray diffraction and FT-IR spectroscopy. Single crystal structure determinations of (L-1)(2)Fe2+(FeCl4-)(2), (L-2)(2)Fe2+FeCl42- and (L-2)(2)Fe2+(FeCl4-),(THF)(4) all show six-coordinate metal center. These complexes were obtained from (LFeCl2)-Fe-1 and (LFeCl2)-Fe-2 during recrystallization attempts. (L-1)(2)Fe2+ was shown to be a high-spin complex, whereas (L-2)(2)Fe2+ was shown to be low-spin. For (L-2)(2)Fe2+FeCl42-, two independent dications of very similar geometry but with distinctive distortion were observed by X-ray analysis. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.10.001
• 作为产物：
  描述：

  2,6-bis-(3-(2,4,6-trimethylphenyl)pyrazol-1-yl)pyridine 、 iron(II) chloride 以 四氢呋喃 为溶剂， 以87%的产率得到FeCl2[2,6-bis(3-mesitylpyrazol-1-yl)pyridine]
  参考文献：
  名称：

  Iron complexes of terdentate nitrogen ligands: formation and X-ray structure of three new dicationic complexes

  摘要：

  Dicationic iron complexes were obtained upon complexation of the ligands 6,6"-di(p-tolyl)-2,2':6',2"-terpyridine (L-1) or 2,6-bis(3-tnesitylpyrazol-1-yl)pyridine (L-2) with iron dichloride or iron trichloride. They were characterized by X-ray diffraction and FT-IR spectroscopy. Single crystal structure determinations of (L-1)(2)Fe2+(FeCl4-)(2), (L-2)(2)Fe2+FeCl42- and (L-2)(2)Fe2+(FeCl4-),(THF)(4) all show six-coordinate metal center. These complexes were obtained from (LFeCl2)-Fe-1 and (LFeCl2)-Fe-2 during recrystallization attempts. (L-1)(2)Fe2+ was shown to be a high-spin complex, whereas (L-2)(2)Fe2+ was shown to be low-spin. For (L-2)(2)Fe2+FeCl42-, two independent dications of very similar geometry but with distinctive distortion were observed by X-ray analysis. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.10.001