The invention provides a stretch blow molded container formed from a thermoplastic resin material which comprises polyglycolic acid having
(a) a repeating unit represented by the following formula (1):
(b) a melt viscosity, η* [as measured at a temperature of (the melting point, Tm of the polymer + 20°C) and a shear rate of 100/sec] of 500-100,000 Pa·s;
(c) a melting point, Tm of at least 180°C;
(d) a melt enthalpy, ΔHm of at least 20 J/g; and
(e) a density of at least 1.50 g/cm3 as measured in an unoriented, crystallized form,
wherein the stretch blow molded container has tensile strength (in a circumferential direction) of at least 100 MPa and a carbon dioxide permeability (as measured at a temperature of 23°C and 80% relative humidity; in terms of the thickness of 50 µm) of 300 cc/m2·day·atm or smaller at the body sidewall thereof, and a production process thereof.
本发明提供了一种由热塑性
树脂材料制成的拉伸吹塑成型容器,这种
树脂材料包括聚
乙二醇酸,具有以下特性
(a) 由下式(1)表示的重复单元:
(b) 熔体粘度η*[在温度为(聚合物熔点Tm+20℃)和剪切速率为100/秒时测得]为500-100,000帕-秒;
(c) 熔点 Tm 至少为 180°C;
(d) 熔体焓 ΔHm 至少为 20 焦耳/克;以及
(e) 密度至少为 1.50 g/cm3 (以未取向的结晶状态测量)、
其中,拉伸吹塑容器的拉伸强度(圆周方向)至少为 100 兆帕,容器体侧壁的
二氧化碳渗透率(在温度为 23℃、相对湿度为 80%的条件下测量;以 50 微米的厚度计)为 300 毫升/平方米-天-阿特米或更小,以及其生产工艺。