[Ru(η(5)-C5Me5)(Me2NCH2CH2NMe2)(O2)][B(3,5-C6H3(CF3)2)4] | 199274-58-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ru(η(5)-C5Me5)(Me2NCH2CH2NMe2)(O2)][B(3,5-C6H3(CF3)2)4]
• CAS: 199274-58-3
• 化学式: C₆H₁₆N₂*C₁₀H₁₅*C₃₂H₁₂BF₂₄*O₂*Ru
• 分子量: 1247.72
• InChiKey: ACQGUYRNDFJNNT-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  [Ru(η(5)-C5Me5)(Me2NCH2CH2NMe2)(O2)][B(3,5-C6H3(CF3)2)4] 在 PPh₃ 作用下， 生成 [Ru(η(6)-tetramethylfulvalene)(Me2NCH2CH2NMe2)(OH)][B(3,5-C6H3(CF3)2)4]
  参考文献：
  名称：

  [Ru(η⁵-C₅Me₅)(Me₂NCH₂CH₂NMe₂)]⁺, a Stable 16-Electron Complex. Reaction with Dioxygen and Formation of a Monomeric Hydroxoruthenium Tetramethylfulvene Complex

  摘要：

  NaBAr4' (Ar' = 3,5-C6H3(CF3)(2)) abstracts chloride from Ru(eta(5)-C5Me5)(Me2NCH2CH2NMe2)Cl (1) in Et2O to give the stable cationic 16e complex [Ru(eta(5)-C5Me5)(Me2NCH2CH2NMe2)]BAr4' (2). Exposure of a Et2O solution of 2 to air at room temperature yields the novel monomeric hydroxotetramethylfulvene complex [Ru(eta(6)-C5Me4CH2)(Me2NCH2CH2NMe2)(OH)]BAr4' (4).

  DOI：

  10.1021/om9706774
• 作为产物：
  描述：

  [Ru(η(5)-C5Me5)(Me2NCH2CH2NMe2)][B(3,5-C6H3(CF3)2)4] 、 氧气 以 乙醚 为溶剂， 生成 [Ru(η(6)-tetramethylfulvalene)(Me2NCH2CH2NMe2)(OH)][B(3,5-C6H3(CF3)2)4] 、 [Ru(η(5)-C5Me5)(Me2NCH2CH2NMe2)(O2)][B(3,5-C6H3(CF3)2)4]
  参考文献：
  名称：

  [Ru(η⁵-C₅Me₅)(Me₂NCH₂CH₂NMe₂)]⁺, a Stable 16-Electron Complex. Reaction with Dioxygen and Formation of a Monomeric Hydroxoruthenium Tetramethylfulvene Complex

  摘要：

  NaBAr4' (Ar' = 3,5-C6H3(CF3)(2)) abstracts chloride from Ru(eta(5)-C5Me5)(Me2NCH2CH2NMe2)Cl (1) in Et2O to give the stable cationic 16e complex [Ru(eta(5)-C5Me5)(Me2NCH2CH2NMe2)]BAr4' (2). Exposure of a Et2O solution of 2 to air at room temperature yields the novel monomeric hydroxotetramethylfulvene complex [Ru(eta(6)-C5Me4CH2)(Me2NCH2CH2NMe2)(OH)]BAr4' (4).

  DOI：

  10.1021/om9706774