(3-((3-(allyloxy)naphthalen-2-yl)oxy)prop-1-yn-1-yl)silver | 1428947-54-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (3-((3-(allyloxy)naphthalen-2-yl)oxy)prop-1-yn-1-yl)silver
• CAS: 1428947-54-9
• 化学式: C₁₆H₁₃AgO₂
• 分子量: 345.146
• InChiKey: SFLSBZFSHAWKDF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.29
• 重原子数：
  19.0
• 可旋转键数：
  5.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  (3-((3-(allyloxy)naphthalen-2-yl)oxy)prop-1-yn-1-yl)silver 、 水 、 silver trifluoroacetate 以 甲醇 为溶剂， 以64%的产率得到
  参考文献：
  名称：

  Assembly of organosilver(I) frameworks with terminal ethynide and ethenyl groups on separate pendent arms attached to an aromatic ring

  摘要：

  A series of eight silver(I) trifluoroacetate complexes based on aromatic ligands bearing terminal ethynyl and ethenyl groups on separate pendent arms has been synthesized. Single-crystal X-ray analysis of the complexes provided detailed information on the influence of argentophilicity, ligand disposition and orientation, and the co-existence of three types of silver-carbon bonding (silver-ethynide, silver-ethenyl and silver-aromatic) in coordination network construction, as well as the roles played by weak pi-pi stacking and anion-pi interactions in supramolecular assembly. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.06.082
• 作为产物：
  描述：

  2,3-二羟基萘 在 potassium carbonate 、 三乙胺 作用下， 以 丙酮 、 乙腈 为溶剂， 反应 2.42h， 生成 (3-((3-(allyloxy)naphthalen-2-yl)oxy)prop-1-yn-1-yl)silver
  参考文献：
  名称：

  Assembly of organosilver(I) frameworks with terminal ethynide and ethenyl groups on separate pendent arms attached to an aromatic ring

  摘要：

  A series of eight silver(I) trifluoroacetate complexes based on aromatic ligands bearing terminal ethynyl and ethenyl groups on separate pendent arms has been synthesized. Single-crystal X-ray analysis of the complexes provided detailed information on the influence of argentophilicity, ligand disposition and orientation, and the co-existence of three types of silver-carbon bonding (silver-ethynide, silver-ethenyl and silver-aromatic) in coordination network construction, as well as the roles played by weak pi-pi stacking and anion-pi interactions in supramolecular assembly. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.06.082