S,S'-bis-{2-(4-benzylidenaminobenzo-15-crown-5)}dithioglyoxime | 151985-15-8

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: S,S'-bis-{2-(4-benzylidenaminobenzo-15-crown-5)}dithioglyoxime
• CAS: 151985-15-8
• 化学式: C₄₄H₅₀N₄O₁₂S₂
• 分子量: 891.033
• InChiKey: BTHBEYRUSKJKLP-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  cobalt(II) chloride hexahydrate 、 S,S'-bis-{2-(4-benzylidenaminobenzo-15-crown-5)}dithioglyoxime 在 吡啶 、 氧气 作用下， 以 乙醇 为溶剂， 以95.1%的产率得到
  参考文献：
  名称：

  The synthesis and characterization of novel dioximes and their heteronuclear complexes containing crown ether moieties

  摘要：

  A novel vic-dioxime S,S'-bis[2-(4'-benzylidenamino-benzo-15-crown-5)]dithioglyoxime (6), with crown ether groups has been synthesized from the reaction of 4'-formylbenzo(15-crown- 5) and S,S'-bis(2-aminophenyl)dithioglyoxime (4), which has been synthesized from the potassium salt of 2-aminothiophenol and dichloroglyoxime. Mononuclear complexes with a metal: ligand ratio of 1:2 have been isolated for nickel(II) and cobalt(III). The reaction of mononuclear complexes with copper(I) and cadmium(II) gives heterotrinuclear complexes. The structure of dioximes and their complexes are proposed according to elemental analyses, H-1 and C-13 NMR, IR, UV-vis and mass spectra.

  DOI：

  10.1016/s0277-5387(00)84371-5