(Me4EtC5)Re(SC2H4S)2 | 461393-09-9

• 英文名称: (Me4EtC5)Re(SC2H4S)2
• CAS: 461393-09-9
• 化学式: C₁₅H₂₅ReS₄
• 分子量: 519.834
• InChiKey: SFMYVIBXRWTDGF-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  双(三甲基硫化硅) 、 (Me4EtC5)ReCl2(SC2H4S) 、 甲苯 以 乙腈 为溶剂， 以30%的产率得到(Me4EtC5)Re(S)(SC2H4S)*1/7C7H8
  参考文献：
  名称：

  Syntheses of a Cp‘ReS Derivative and More Complex Products

  摘要：

  The reaction of Cp'ReCl2S3 (CP' = Me4EtC5) with slightly less than 2 equiv of a phosphine reagent results in the formation of [Cp'Re(Cl)(2)(mu-S)](2), 2, which has been characterized by an X-ray diffraction study. Reactions of 2 with nucleophiles did not lead to monomeric derivatives of the type Cp'ReS(Cl)(2)(Nuc). The reaction of Cp'ReCl2(SC2H4S) with (Me3Si)(2)S resulted in the formation of three new products: Cp'ReS(SC2H4S), 4; Cp'Re(S-3)(SC2H4S), 5; and a tetranuclear derivative, [(Cp'Re)(2)(mu-S) (mu,eta(2)-SC2H4S)(mu,eta(1)-SC2H4S](2)Cl-2, 6. Complexes 4 and 6 have been characterized by X-ray diffraction studies. The electrochemical properties of the mononuclear Re=S derivative, 4, are compared with those of Re=O and Re=NR analogues.

  DOI：

  10.1021/ic0206241