cis-[PtCl2(SMe2)AsPH3] | 430430-98-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cis-[PtCl2(SMe2)AsPH3]
• 英文别名: dichloroplatinum;methylsulfanylmethane;triphenylarsane
• CAS: 430430-98-1
• 化学式: C₂₀H₂₁AsCl₂PtS
• 分子量: 634.36
• InChiKey: VNJLLUSJOHLKLM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dichlorobis(dimethylsulfide)platinum(II) 、 三苯胂 以 氯仿 为溶剂， 生成 cis-[PtCl2(SMe2)AsPH3]
  参考文献：
  名称：

  Quantifying the trans influence of triphenylarsine. Crystal and molecular structures of cis-[PtCl2(SMe2)(AsPh3)] and cis-[PtCl2(AsPh3)2]·CHCl3

  摘要：

  Reaction between a mixture of cis-trans-[PtCl2(SMe2)(2)] and 1 eqiv. AsPh3 in chloroform gives Cis-[PtCl2(SMe2)(AsPh3)] crystallizing in P2(1)/n with a = 10.397(2), b = 14.876(3), c = 13.956(3) Angstrom, beta = 90.86(3)degrees and Z = 4. Selected geometrical parameters are Pt-As 2.3531(10), Pt-S 2.262(2), Pt-Cl (trans to S) 2.301(2), Pt-Cl (trans to As) 2.328(2) Angstrom and S-Pt-As 88.85(6), S-Pt-Cl(2) 90.77(8), As-Pt-Cl(1) 91.07(6) and Cl-Pt-Cl 89.42(7)degrees, cis-[PtCl2(AsPh3)(2)].CHCl3 crystallizes in P2(1)/c with a = 20.557(4), b = 9.5951(19), c = 20.147(4) Angstrom, beta = 96.77(3)degrees and Z = 4. Selected geometrical parameters are Pt-As(1) 2.3599(9), Pt-As(2) 2.3770(9), Pt-Cl(1) (trans to As(1)) 2.3515(18), Pt-Cl(2) (trans to As(2)) 2.3251(18) Angstrom and As-Pt-As 97.87(3), As(1)-Pt-Cl(2) 88.67(5), As(2)-Pt-Cl(1) 84.30(5) and Cl-Pt-Cl 89.32(7)degrees. By comparison with related structures from the literature the following trans influence series was established PMe2Ph > PPh3 > AsPh3 approximate to SbPh3 > Me2SO approximate to SMe2 approximate to SPh2 > NH3 approximate to olefin > Cl- > MeCN. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00785-x