{1-benzyl-3-benzoyl-imidazolin-2-yliden}chlorogold(I) | 150112-73-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: {1-benzyl-3-benzoyl-imidazolin-2-yliden}chlorogold(I)
• CAS: 150112-73-5
• 化学式: C₁₇H₁₄AuClN₂O
• 分子量: 494.73
• InChiKey: VBFOFMPOTYCCOE-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  tris{μ-(1-benzylimidazolato-N(3),C(2))}tri-gold(I) 、 苯甲酰氯 以 二氯甲烷 为溶剂， 以88%的产率得到{1-benzyl-3-benzoyl-imidazolin-2-yliden}chlorogold(I)
  参考文献：
  名称：

  Reactions of trimeric 1-benzyl-2-gold(I)imidazole leading to AuI carbene complexes. Crystal structure of [1-benzyl-3-benzoyl-imidazolin-2-yliden]chlorogold(I)

  摘要：

  The crystal structure determination of a compound previously described as tris-[{mu-(N1-benzyl)imidazolato-N3,C2}(chloro)benzoylgold(III)], which turned out to be a gold(I) mononuclear carbene derivative, has led to a reconsideration of the reactions of [Au3im3] (im = mu-(N1-benzyl)imidazolato-N3,C2) with reagents X-Y. The mononuclear or trinuclear nature of other Au imidazolyl derivatives is discussed and the compounds obtained by reaction with X-Y = Cl-COOEt, I-Et or Cl-p-tosyl and chlorobenzoyl appear to e mononuclear, whereas those obtained by reaction with Me3SiI, SOCl2 or I2 appear to be trinuclear mixed valence or gold(III) compounds.

  DOI：

  10.1016/0022-328x(93)83204-9