{dirhodium(II)(μ-O2CCF3)3(η1-O2CCF3)(η2-P(2-ClC6H4)Ph2)(H2O)} | 151339-31-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: {dirhodium(II)(μ-O2CCF3)3(η1-O2CCF3)(η2-P(2-ClC6H4)Ph2)(H2O)}
• CAS: 151339-31-0
• 化学式: C₂₆H₁₆ClF₁₂O₉PRh₂
• 分子量: 972.626
• InChiKey: JFKVUYXJNJXGLU-UHFFFAOYSA-J

反应信息

• 作为反应物：
  描述：

  {dirhodium(II)(μ-O2CCF3)3(η1-O2CCF3)(η2-P(2-ClC6H4)Ph2)(H2O)} 以 二氯甲烷 为溶剂， 以88%的产率得到
  参考文献：
  名称：

  Simultaneous substitution of bridging acetate groups and reversible RhC bond cleavage in [Rh2(O2CCH3)3-{(C6H4)PPh2}(HO2CCH3)2] in the presence of CF3CO2H. Crystal structure of [Rh2(O2CCF3)3-{(C6H4)PPh2}(HO2CCF3)2]

  摘要：

  The reaction of the monometallated compound [Rh2(O2CCH3)3 {(C6H4)PPh2}(HO2CCH3)2] (1) with CF3CO2H at room temperature yields [Rh2(O2CCF3)3{(C6H4)PPh2}(HO2CCF3)2] (3) as the only isolable product. Compound 3 has been characterized by X-ray methods. 3 crystallizes in the space group P2, In. It contains three trifluoroacetate groups bridging a Rh(2)4+ unit with a Rh-Rh bond distance of 2.438(1) angstrom; the fourth bridging ligand is a triphenylphosphine metallated at one of the ortho positions. Two molecules of trifluoroacetic acid occupy the axial coordination positions. In addition to the substitution of acetate groups, reversible electrophilic Rh-C bond activation is observed.

  DOI：

  10.1016/0022-328x(93)80223-x
• 作为产物：
  描述：

  、 三氟乙酸 以 三氟乙酸 为溶剂， 以80%的产率得到{dirhodium(II)(μ-O2CCF3)3(η1-O2CCF3)(η2-P(2-ClC6H4)Ph2)(H2O)}
  参考文献：
  名称：

  Simultaneous substitution of bridging acetate groups and reversible RhC bond cleavage in [Rh2(O2CCH3)3-{(C6H4)PPh2}(HO2CCH3)2] in the presence of CF3CO2H. Crystal structure of [Rh2(O2CCF3)3-{(C6H4)PPh2}(HO2CCF3)2]

  摘要：

  The reaction of the monometallated compound [Rh2(O2CCH3)3 {(C6H4)PPh2}(HO2CCH3)2] (1) with CF3CO2H at room temperature yields [Rh2(O2CCF3)3{(C6H4)PPh2}(HO2CCF3)2] (3) as the only isolable product. Compound 3 has been characterized by X-ray methods. 3 crystallizes in the space group P2, In. It contains three trifluoroacetate groups bridging a Rh(2)4+ unit with a Rh-Rh bond distance of 2.438(1) angstrom; the fourth bridging ligand is a triphenylphosphine metallated at one of the ortho positions. Two molecules of trifluoroacetic acid occupy the axial coordination positions. In addition to the substitution of acetate groups, reversible electrophilic Rh-C bond activation is observed.

  DOI：

  10.1016/0022-328x(93)80223-x