| 849437-41-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 849437-41-8
• 化学式: C₄₉H₆₀CoN₅O₄
• 分子量: 842.04
• InChiKey: OBGJMAIWIDUAFF-MAWOECAXSA-L

反应信息

• 作为反应物：
  描述：

  以 甲醇 、 二氯甲烷 为溶剂， 生成 cobalt(2+);(E)-N,N'-dioxido-1,2-bis(2,4,6-trimethylphenyl)ethane-1,2-diimine;hydron;pyridine
  参考文献：
  名称：

  Co−C Bond Homolysis:  Reactivity Difference between Alkyl- and Benzylcobaloximes

  摘要：

  The Co-C bond is activated toward homolysis due to the interactions between axial and equatorial dioxime ligands. Benzylcobaloxime gives an oxygen-inserted product, whereas the alkyl derivative forms air-stable cobalt(II). The stabilization of the axial R group due to the interaction between axial and equatorial ligands causes the reactivity difference.

  DOI：

  10.1021/om070053q