bis{N-[2-[(Z)-2-hydroxyethyliminomethyl]phenyl]-4-methylbenzenesulfonamide}zinc(II) | 130725-45-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis{N-[2-[(Z)-2-hydroxyethyliminomethyl]phenyl]-4-methylbenzenesulfonamide}zinc(II)
• CAS: 130725-45-0
• 化学式: C₃₂H₃₄N₄O₆S₂Zn
• 分子量: 700.167
• InChiKey: QQZBWGDFXWDLCT-MLQPTNSWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-(o-tosylaminobenzylidene)-2-hydroxyethylamine 、 zinc diacetate 以 甲醇 为溶剂， 生成 bis{N-[2-[(Z)-2-hydroxyethyliminomethyl]phenyl]-4-methylbenzenesulfonamide}zinc(II)
  参考文献：
  名称：

  Garnovskii, A. D.; Alekseenko, V. A.; Burlov, A. S., Koordinatsionnaya Khimiya, 1990, vol. 16, p. 472 - 476

  摘要：

  DOI：

文献信息

• Complexes of zinc(II) with N-[2-(hydroxyalkyliminomethyl)phenyl]-4-methylbenzenesulfonamides: synthesis, structure, photoluminescence properties and biological activity
  作者：A.S. Burlov、V.G. Vlasenko、Yu.V. Koshchienko、N.I. Makarova、A.A. Zubenko、Yu.D. Drobin、G.S. Borodkin、A.V. Metelitsa、Ya.V. Zubavichus、D.A. Garnovskii

  DOI：10.1016/j.poly.2018.01.020

  日期：2018.4

  The synthesis of a series of zinc(II) complexes with Schiff bases products of condensation of 2-tosylamonobenzaldehide with various aminoalcohols containing aliphatic spacers of a variable length (CH2)(n) (n = 2-6) was performed. All compounds were characterized with C, H, N elemental analysis, FT-IR, H-1 NMR, X-ray absorption spectroscopy, UV-Vis and photoluminescence data. The local atomic structures of complexes were determined by X-ray absorption spectroscopy from analysis of EXAFS and XANES of Zn K-edges. The electronic absorption spectra, photoluminescence, and biological activities of the complexes were investigated. The assignments of the experimental UV-Vis spectra of zinc(II) complexes have been carried out by Time-Dependent Density Functional Theory TD-DFT calculations. (C) 2018 Elsevier Ltd. All rights reserved.