mer-(Ph4P)[Fe(CN)3(8-(pyrazine-2-carboxamido)quinoline(-H))] | 956149-47-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: mer-(Ph4P)[Fe(CN)3(8-(pyrazine-2-carboxamido)quinoline(-H))]
• CAS: 956149-47-6
• 化学式: C₁₇H₉FeN₇O*C₂₄H₂₀P
• 分子量: 722.548
• InChiKey: WDAPBVXFTLKVDN-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  [Mn^III(salen)(H₂O)]ClO₄ 、 mer-(Ph4P)[Fe(CN)3(8-(pyrazine-2-carboxamido)quinoline(-H))] 以 甲醇 为溶剂， 生成 [Mn(salen)][Fe(CN)3(pzcq)]*4H2O
  参考文献：
  名称：

  Ferrimagnetic Fe^III−Mn^III Zigzag Chain Formed by a New mer-Positioned Iron(III) Cyanide Precursor

  摘要：

  A new cyanide-bearing molecular precursor, mer-[Fe(pzcq)(CN)(3)](-) (1), and a zigzag chain, [Fe(pzcq)(CN)(3)][Mn(salen)]center dot 4H(2)O (2), were prepared and characterized in terms of structure and magnetism. Magnetic data reveal that intrachain antiferromagnetic couplings via cyanide ligands in 2 are clearly operating, resulting in a ferrimagnetic nature.

  DOI：

  10.1021/ic701361a